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Use of ZnO:Mn particles for degradation of methylene blue by photocatalysis process

Abstract

The management of water use in the agricultural environment is a key factor to build new environmentally sustainable productive methods. Photocatalysis is a promising method for water decontamination. This research paper aimed to evaluate the photocatalytic potential of pure and Mn-doped ZnO particles. The materials were obtained by the polymeric precursor method, and characterized by X-ray diffraction, N2 adsorption in low temperature, infrared and ultraviolet spectroscopy, and photoluminescence. In order to evaluate ZnO:Mn particles photoefficiency, experiments were carried out by applying the methylene blue dye solution to photodegradation under UVC exposure. The particles had ZnO single-phase, but low specific surface area. The sample ZnO:0.25% Mn presented higher efficiency in the methylene blue photocatalytic degradation test. This efficiency was related to a higher band gap energy value and a lower rate of electron recombination, which allows greater formation of hydroxyl radicals, which are responsible for dye degradation.

Keywords:
ZnO; particles; photocatalyts

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