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Synthesis and characterization of Ca2CoTaO6, a new monoclinically distorted double perovskite

The new Ca2CoTaO6 double perovskite has been synthesized by a conventional solid state reaction and its unit cell parameters determined by X-ray powder diffractometry. It crystallizes in the monoclinic space group P2(1)/n. The unit cell parameters are: a = 5.507(2) Å; b = 5.564(3) Å; c = 7.798(3) Å; β = 89.99(4)° and Z = 2. The IR spectrum of the material was recorded and is briefly discussed. Some comparisons with Ca2CoNbO6 and other isostructural perovskites are also performed.

Ca2CoTaO6; double perovskite; X-ray diffraction; IR spectrum


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