Ultrafine quartz flocculation: Part II. Main variables

Abstract

Flocculation is a complex process, usually dependant on various conditions to perform adequately. Nevertheless, the relevance and interaction of the process variables are not easily found in literature. In this study, nine variables of ultrafine quartz flocculation systems, defined in Part 1 of this study, were analysed. The effects of each variable and their interactions in the system were investigated based on flocculation and sedimentation tests. The results were statistically evaluated using the supernatant turbidity as experimental response. The evaluations resulting from the statistical approach indicated that suspension pH (5.49%) was the most significant variable, followed by flocculant concentration (4.07%) with the second greatest effect on the turbidity of the supernatant. Solid concentration, agitation intensity, and surfactant conditioning time (4.05%, 3.51% and 3.51%, respectively), also have significant effects on ultrafine quartz flocculation. The flocculant concentration and the surfactant conditioning time were the variables with the most significant interactions with the main variables. The Camp Number values showed a negative exponential relationship with the turbidity results, proving to be an important tool to evaluate flocculation. Backscattered electron scanning microscopy images of flocs formed in the presence of 30 g/t PAM showed compact flocs in the size range between 150 and 365 µm, with noticeable sphericity.

Keywords:
flocculation; ultrafine quartz; turbidity; Camp Number; fractioned factorial method