We initially review basic concepts of the forces acting on soil water, soil water potential and soil water retention, and equations to describe soil water movement under water-saturated and unsaturated conditions. Processes of infiltration, evaporation and redistribution of water will be presented for simple initial and boundary conditions occurring within homogeneous soil columns. Next we consider the physical, chemical and biological processes within a soil profile that distribute, dilute or concentrate solute species within the liquid phase of a soil The relative concentration of solutes in the liquid phase governs not only the retention and transport of water within soils but also contributes to our understanding of managing the quality of water within soils and that moving below the recall of plant roots deeper into the vadose zone. A complete set of references about this subject is available in Kutílek & Nielsen (1994). In the last section we recall the differences between classical statistical concepts and those that utilize the coordinates of space and time at which state variables across the landscape are observed. Our presentation win cover the basic ideas about autocorrelation, crosscorrelation, applied time series analyses, state space analyses and similar techniques currently being used to enhance field research and investigations of land and water management.
Solute transport; regionalized variable