Boron Doped Ultrananocrystalline Diamond Films on Porous Silicon: Morphological, Structural and Electrochemical Characterizations

Abstract

Boron doped ultrananocrystalline diamond (BDUND) films were grown and characterized on porous silicon (PS) substrates. PS samples were prepared from n-type monocrystalline silicon wafers (100) with 1-20 Ω.cm of resistivity, by electrochemical etching, using HF-acetonitrile solution as electrolyte. BDUND films were grown by Hot Filament Chemical Vapor Deposition using CH₄, H₂ and Ar. The doping process consisted of an additional hydrogen line, passing through a bubbler containing B₂O₃ dissolved in methanol, with boron/carbon ratio of 20000 ppm in solution. Raman spectroscopy and X-Ray diffraction were used to evaluate the quality of the films. Scanning electron microscopy was used for morphological characterization, and confirmed that the films covered the pores without filling them. Electrochemical response and capacitance behavior of the electrodes were explored, by cyclic voltammetry. Samples presented high capacitance, confirming that BDUND/PS electrodes are promising for application as electrochemical capacitors.

Keywords:
boron doped ultrananocrystalline diamond films; porous silicon; electrochemical application; capacitance

1 Introduction

Porous silicon, which consists of a superficial film with randomly spaced pores, can be obtained by chemical or electrochemical etching of silicon, in hydrofluoric acid solution¹. The dissolution process is a function of current density, electrolyte concentration, crystal orientation, resistivity and light intensity, which affect pore size and porosity². The conventional method for obtaining PS is through anodizing process under galvanostatic conditions³. PS presents extremely rich morphological features and it is a very attractive material for biomedical applications, solar cells, gas sensors, light emitting diodes, among others^4-7. Furthermore, PS has been used as substrate to thin films growth, including diamond films, in order to increase the number of diamond nucleation sites, improving the films crystalline structure. It presents a large surface area, which makes it an excellent material for obtaining porous electrodes^8,9.

One of the most common methods to grow diamond films is the Chemical Vapor Deposition (CVD) process, which involves gas phase chemical reactions on the substrate surface and results in the deposition of a solid material¹⁰. Typically, the gas mixture used to obtain diamond films consists of hydrogen and methane. For nanofilms, an inert gas, such as argon or helium, is used in addition to the mixture of hydrogen and methane, in order to promote a continuous transition of grain size from micro to nanocrystalline¹¹. Since diamond surface has a high resistivity, doping with boron is performed in order to obtain semiconducting characteristics. Diamond p-type doping has been achieved by boron substitutional process during the film growth¹².

For diamond growth, PS can influence the nucleation, strain and crystal structure of the films grown on its surface. CVD diamond nucleation occurs preferentially at active sites such as surface defects, vertices and atoms edges. The combination of PS morphology control, associated to its pre-treatment, may be mandatory to obtain good quality diamond films¹³. Thus, the nucleation and growth of the diamond film depends on the PS roughness and porosity, besides thermodynamic deposition parameters¹⁴.

The establishment of a doping method of CVD diamond films allowed a wide range of application possibilities of these semiconductor films in different areas of science. One of the applications that aroused most interest was the electrodes manufacture to use in electrochemical applications¹². Boron doped diamond films grown on porous electrodes have shown excellent electrochemical properties associated with their surface area and dopant concentration¹⁵. Thus, electrochemical studies have shown that nanocrystalline diamond (NCD)/PS electrodes have high capacitive background current, mainly due to the large surface area, making them excellent electrochemical capacitors⁸.

Since NCD/PS has show to be a great material for electrochemical applications, in this work, BDUND films were grown on PS, in order to produce not only a porous material, but a boron doped electrode. PS substrates were characterized by Scanning Electron Microscopy (SEM) and Raman scattering spectroscopy. Morphological and structural characterization of BDUND/PS electrodes were made by SEM, Raman spectroscopy and X-ray diffraction. Electrochemical characterization was performed by cyclic voltammetry.

2 Experimental Procedures

Porous silicon samples were obtained from n-type monocrystalline silicon wafers (100) with 1-20 Ω.cm of resistivity, by electrochemical etching, using HF-acetonitrile solution as electrolyte. The silicon backside was previously covered with indium to promote a good ohmic contact. The electrodes were polarized under current density of 56.5 mA/cm² for 120 min while a 50 W dichroic lamp was positioned above the system. After anodization, samples were rinsed in deionized water and dried in nitrogen gas.

BDUND films were grown by Hot Filament Chemical Vapor Deposition (HFCVD) technique using CH₄, H₂ and Ar. Films were deposited on PS substrate after seeding pretreatment, in PDDA polymer solution and KCl colloidal solution containing 4 nm diamond particles^16,17. The doping process consisted of an additional hydrogen line, passing through a bubbler containing B₂O₃ dissolved in methanol, with boron/carbon ratio of 20000 ppm in solution. There were used five linear tungsten wires with 125 µm of diameter as filaments, placed side by side with a 7 mm distance between them. The applied current was 15 A and the pressure inside the reactor was 30 Torr. One film was grown for 3h, using 18/1.5/80 sccm of H₂/CH₄/Ar. Another one was grown for 4h, using 18.5/1.0/80 sccm of H₂/CH₄/Ar.

PS as well as BDUND/PS morphologies were analyzed by SEM images using a JEOL JSM-5310 microscope system, whereas their structural characterizations were made by micro-Raman scattering spectroscopy using a Renishaw microscope system 2000. In addition, BDUND/PS patterns were obtained by X-ray diffraction using a high resolution Philips difractometer, X'Pert model, with the CuK_α1 radiation (λ = 0.154 nm) in grazing incident mode with an incident angle of 1°. The average grain size was estimated by Scherrer equation¹⁸, from the broadening of X-ray <111> peak. In order to confirm the average grain size, Field Emission Gun (FEG)-SEM images were made by a TESCAN MIRA 3 microscope system.

Electrochemical characterizations were made by cyclic voltammetry, which was performed at room temperature, using a potentiostat AUTOLAB – PGSTAT 302. It was used 0.5 mol/L H₂SO₄ as electrolyte at a scan rate of 50 mV/s. A three electrode system was used in this study, consisting of a work electrode (sample), a counter electrode (platinum) and a reference electrode (Ag/AgCl).

3 Results and Discussion

SEM images of PS sample obtained by electrochemical etching are presented in Figure 1, in two different magnifications. As observed in the image, PS shows large pores uniformly distributed over the surface. This morphology provides large surface area, making it ideal for diamond films growth.

Figure 1
SEM images of porous silicon, in different magnifications (a) 1000x (b) 5000x.

Figure 2 shows the Raman spectrum of PS sample. It presents the silicon peak shifted to 518 cm^–1 from the crystalline silicon peak, 520.5 cm^–1, which is typical of porous silicon¹⁹. The photoluminescence band, centered in approximately 4300 cm^–1, is also a PS feature²⁰.

Figure 2
Raman spectrum of porous silicon.

BDUND films were grown for 3 and 4h on PS substrates. Figure 3 shows SEM images of these samples. Both of them presented good nucleation and films coalescence, with uniform morphology. BDUND films covered the bottom and the top surfaces of the pores, as well as its walls, without filling them, keeping the suitable sample porosity.

Figure 3
SEM images of BDUND grown on PS for (a) 3h and (b) 4h.

It is known that the presence of pores on the Si surface increases the nucleation density of carbonaceous materials. The nucleation density on PS is far higher than that on monocrystalline Si. One possible explanation for this is the fact that PS is almost entirely covered by hydrogen atoms²¹. The atomic hydrogen on PS surface stabilizes the formation of the C-H bond, which is a primary precursor to diamond crystallization, and also attacks the amorphous carbon that blocks the nucleation of diamond. Moreover, PS displays a large number of surface defects, which increases the formation of nuclei for diamond growth¹³. Thus, it was possible to obtain homogeneous diamond films on PS with growth times of 3 and 4h, which is considered a quite fast process for CVD diamond films.

Figure 4 shows Raman spectra of BDUND/PS electrodes grown in 3 and 4h. As can be seen, both spectra showed ultrananocrystalline diamond (UNCD) features, such as, the D band (1345 cm^–1), which arises due to sp² disorder, and the G band (1550 cm^–1), related to sp² amorphous carbon. The band around 2670 cm^-1 is called G'. This band and other remaining peaks of lesser intensity in the high frequencies region can be assigned to overtones (frequency higher than the fundamental frequency), and combinations of modes, i.e., processes that involve two or more phonons, the fundamental vibrations modes of small cross section or double resonance processes^22,23.

Figure 4
Raman spectra of BDUND grown on PS for (a) 3h and (b) 4h.

Furthermore, the spectra do not present a diamond one-phonon line around 1332 cm^–1, as it is verified for single crystal diamond, because this peak was hidden by the strong scattering of sp² carbon components in these films. Besides, the broadening of this peak, related to the D band present at 1345 cm^–1, overlapped the diamond peak. This behavior is usually noted in NCD using Raman excitation in the visible region²⁴.

For NCD and UNCD films, the shoulders at 1150 cm^–1 and 1490 cm^–1 have been ascribed to the transpolyacetylene (TPA) segments presence at the grain boundaries²⁵. Nonetheless, in more recent paper, authors did not agree with this analysis. They used Raman spectroscopy with different wavelengths and discussed the TPA decomposition at temperature lower than that for the film growth. In conclusion, the peak at 1150 cm^–1 was attributed to the deformation mode of the CH_x bond²⁶.

The X-ray diffraction patterns of the BDUND/PS electrodes are presented in Figure 5. Although films present lower thickness, it is possible to observe the peaks at 43.9°, 75.3° and 91.5° corresponding to the 〈111〉, 〈220〉 and 〈311〉 diamond diffraction peaks, which confirm the presence of crystalline diamond²⁷. In addition, two silicon peaks at 47° (220) and 56° (331) can be seen. Despite the measures have been made with grazing angle of 1.0°, it was detected the Si presence in both samples, since the films are very thin and the X-ray penetration depth is very high in carbonaceous materials.

Figure 5
X-ray diffraction spectra of BDUND grown on PS for (a) 3h and (b) 4h.

It is also possible to observe peaks at 57° and 88°, probably associated with silicon carbide (SiC). The SiC layer always exists between the diamond and the Si substrate²⁸. In the case of PS substrate, it is easily carbonized during growth due to its porous structure. Thus, the PS layer is almost completely carbonized in a SiC porous layer, resulting in its respective diffraction peaks in the patterns²⁹. This SiC formation, which usually occurs on the edge and top of the pores, can be related to high adhesion between diamond and PS¹⁴.

The average grain size was calculated by Scherrer equation¹⁸, from the <111> peak. The obtained value was around 5 nm. This value indicates that the films might be ultrananocrystalline, which are characterized by presenting grain size range from 2 to 10 nm^[24]. FEG-SEM images were made to confirm this assumption and are shown in Figure 6. The films exhibit non-columnar growth, which reflects on a surface formed by agglomerates of grains, characteristic of UNCD films²⁴. Figure 6a shows that the agglomerates sizes are around 240 nm. In Figure 6b, the larger grains inside the agglomerate present size around 11 nm. Smaller grains could not be measured due to equipment limitations (616 kx) in a good focal view. However, these images evidenced the films ultrananocrystalline morphologies.

Figure 6
FEG-SEM images of BDUND/PS, in different magnifications (a) 113000x, showing grains agglomerates (b) 616000x, showing grain sizes.

Electrochemical characterization was made by cyclic voltammetry. It was possible to obtain the work potential window of BDUND/PS electrodes, grown in 3 and 4h, using a BDUND/Si work potential window as comparison parameter, as shown in Figure 7a. The BDUND/Si electrode, used for comparison, also presents doping of 20000 ppm B/C in solution. The current densities were obtained from the geometric area. Figure 7b shows a zoom view of the voltammograms in the central region, in a small potential range, to compare the current background and to highlight the capacitive effect of BDUND/PS.

Figure 7
(a) Work potential windows of BDUND/PS grown for 3h and 4h, and of a BDUND/Si sample, (b) Zoom view of the work potential windows.

As expected for porous electrodes, it is possible to observe the large capacitive effect in black and red curves, which occurs due to the large active area of the BDUND/PS electrodes, as shown in SEM images. These electrodes also showed resistive behavior, which was corrected in the figure by IR compensation. This compensation was performed in the potential region around zero (0.0 V × Ag/AgCl), where it is possible to separate the contribution of the electrode resistance in the current value.

It is also possible to observe that the hydrogen evolution process for BDUND/Si electrode starts at much less negative potential, indicating that this electrode is more conductive. The anodic and cathodic small shoulders appearing in BDUND/PS samples, indicated by (I) and (II) in Figure 7a, represent redox transitions of containing oxygen functional groups, due to the large amount of sp² bonds present in NCD films³⁰.

Considering the anodic current densities for the three electrodes in the zero region potential, it is possible to obtain values ​​of the order of 4.6 × 10^–6; 2.4 × 10^–4 and 1.8 × 10^–4 for the BDUND/Si, BDUND/PS-3h and BDUND/PS-4h electrodes, respectively. These results show a capacitive current of two orders of magnitude higher for samples grown on PS. From these results, it is possible to obtain the electrodes capacitance. The capacitance (C) is the proportionality coefficient between the capacitive current (I) and the scanning speed (v), that is C = I/v. Figure 8 presents the capacitance results for the three electrodes.

Figure 8
Capacitance values for the three electrodes.

The capacitance values ​​increased with the potential, as expected, especially for the films grown on PS. In 0.8 V × Ag/AgCl, these values ​​are around 300, 6500 and 5500 μF.cm^–2 for the BDUND/Si, BDUND/PS-3h and BDUND/PS-4h electrodes, respectively, considering their geometric areas. Therefore, 3h electrode shows a capacitance value more than 20 times higher than that of BDUND/Si sample.

It is important to note that although the capacitance of the 4h film is higher than that of BDUND/Si, the capacitance tended to decrease when increasing growth time. This fact may be associated to a greater covering of the pores with higher growth time, showing that this is also a limiting factor for electrochemical applications where the capacitive effect should be a dominant factor. In this case, the challenge is to obtain a BDUND layer over PS that promotes a uniform and homogeneous film, covering the walls and the bottom of the pores, but maintaining the porous morphology.

Results are consistent with those found by Ferreira and coworkers⁸, in which NCD/PS electrodes showed capacitance values ​​in the range of 230-990 μF.cm^–2 in × 1.0 V × Ag/AgCl. This corresponds to about a 25 times increase, compared to boron doped microcrystalline diamond electrodes. The electrodes capacitance curve, in the studied potential range, presented a similar behavior to that observed in Figure 8, in which the capacitance increases as a function of the potential.

These results also showed good agreement with the values ​​found by Honda and coworkers³¹. For their nanohoneycomb diamond electrode, the capacitance value at 1.0 V × Ag/AgCl was 190 μF.cm^–2, 15 times greater than that for their diamond electrode. They attributed the high capacitance values ​​to the formation of highly ordered porous structure, as well as, to the surface oxidation. The BDUND/PS electrodes obtained in this study showed a capacitance value about 30 times greater than that of nanohoneycomb diamond obtained by Honda et al.³¹.

4 Conclusions

BDUND films were successfully grown and characterized on PS substrate. SEM images confirmed that BDUND films covered the whole PS surface, including the pores bottom and their internal walls, maintaining the substrate porous structure and providing greater surface area, which is ideal for diamond films growth. Structural characterization confirmed the diamond presence. Raman spectra presented the D and G bands, features of UNCD films. In X-ray diffraction patterns, it was possible to observe the peaks corresponding to the 〈111〉, 〈220〉 and 〈311〉 diamond diffraction peaks. FEG-SEM images showed the ultrananocrystalline film morphology. Electrochemical characterization showed high capacitance values for BDUND/PS samples, as expected for porous electrodes, confirming that BDUND/PS electrodes are promising for electrochemical applications.

Acknowledgements

The authors would like to thank CAPES and FAPESP for financial support and M. L. B. Matos for SEM images.

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Publication Dates

• Publication in this collection
  24 Nov 2015
• Date of issue
  Nov-Dec 2015

History

• Received
  29 Sept 2015
• Reviewed
  21 Oct 2015