(5/5) Diclofenac Ibuprofen Carbamazepine Caffeine |
Argentina, Buenos Aires, Córdoba, La Plata, Pampas, Santa Fé, Not reported. |
1 (-, simple, 6) |
SPE (OASIS HBL, MeOH) |
LC (Kinetex PFP o C18, H2O/NH₄CH₃CO₂ /Formic acid + MeOH/AcN/CH3CO2NH4, gradient) |
ESI-MS |
91.1-142.4/ 1-15/ - |
- - - - |
<0.03-1.2 0.4-13, 100 0.2-2.3 0.9-44.2, 100 |
1 |
(4/4) Sulfamethoxazole Trimethoprim |
Bolivia, El Alto, Primary, 2 parallel bars to remove solids. Secondary: 2 series of lagoons with 6 lagoons each series. |
2 (-, simple, 1) |
SPE (OASIS HBL, MeOH/Acetic acid, ILS) |
LC (Waters-Xterra-C18, H2O/ Formic acid + H2O/AcN, gradient, ILS) |
ESI-MS |
76-128/ 1.2-7.6/ MED |
1.3 - |
0.4-1.3 0.27-0.34 |
2 |
(3/3) Diclofenac |
Brasil, Ceará, Primary; secondary, waste stabilization pond: 1 facultative and 2 maturation |
- (0.5L, simple, 2) |
SPE (DSC 18, Acetone / Hexane) |
Potentiostat / Galvanostat |
|
- / 49.5-146.3/ - |
14.0-30.5, 100 |
- |
3 |
(1/1) Diclofenac |
Quebec/Canada, Primary and secondary Clarifier, treatment of UV disinfection. |
1(-, simple, 1) |
SPE (Sep-Pak-Plus-18, MeOH/AcN, ILS) |
LDTD (BetaBasic-C18, H2O/ Acetic acid + AcN/ Acetic acid, isocratic, ILS) |
APCI-qQq/MS |
98.2-104.6/ 1000/ - |
71.6-58.2, 100 |
19.7-12.3,100 |
4 |
(20/31) Atrazine Bisphenol A Caffeine Carbamazepine Diclofenac Estrone Progesterone Sulfamethoxazole |
Quebec/Canada, Not reported |
20 (-, simple, 2) |
SPE (Strata-X- C, ethyl acetate and MeOH /NH4OH, ILS) |
LC (Hypersil-GOLD-C18, H2O/NH4HCO3, MeOH, gradient) |
QqQ-MS/MS |
43-122/ 0.5-104/ MED |
- - - - - - - - |
0.01-0.006 0.59-0.36 27.20-13.42 0.22-0.06 0.04-0.03 0.05-0.03 0.02-0.01 0.09-0.01 |
5 |
(35/56) Acetaminophen Atrazine Bisphenol A Carbamazepine Diclofenac Estrona Ibuprofen Progesterone Sulfamethoxazole Triclosan |
California/EEUU, Primary: screening and sedimentation. Secondary: activated sludge and sedimentation or advanced primary. |
4 (2L, simple, 4) |
F1: SPE (OASIS HBL, MeOH + MeOH/MTBE, ILS) F2: SPE (OASIS HBL, CH2Cl2, ILS) F1: LLE (F1, NaCl, CH2Cl2/hexane, ILS) LLE (F1, F2, Isooctane, ILS) |
LC GC (DB5-MS) |
API, ESI-qQq/MS MS-MS |
80-120/ 0.2-50/ MED |
- - - - - - - - - - |
11.00-ND, 44 0.02-ND, 63 1.60-0.21, 100 0.36-0.22, 100 0.18-0.07, 100 0.12-0.01, 100 12.00-ND, 94 0.05-ND, 63 2.04-0.48, 100 1.50-0.31, 100 |
6 |
(10/13) Caffeine Carbamazepine Ibuprofen Naproxen Sulfamethoxazole Triclosan |
Illinois/EEUU, Primary: Screening bar. Waste stabilization pond Secondary: 2 aerated ponds and sand tank. |
2 (2-4L, simple, 1) |
SPE (OASIS HBL, MeOH + Acetone /MeOH OR ethyl acetate /MeOH + MeOH/H2O, Acetic acid + MeOH/H2O, NH4OH and MeOH/NH4OH, ILS) |
LC (C18, H2O/ NH4OH /Acetic acid + AcN/MeOH OR H2O/ NH4OH + AcN/NH4OH gradient) |
ESI-qQq/MS |
71-116/-/MED |
57.70-51.30 0.067-0.047 26.20-18.60 38.80-19.40 3.80-0.93 5.44-4.65 |
0.49-ND 0.22-0.15 5.03-0.15 0.91-0.06 0.04-0.17 0.22-0.02 |
7 |
(5/5) Bisphenol A Ibuprofen Triclosan |
México/México, Not reported |
4 (1L, simple, 3) |
SPME (Polyethylene Glycol fiber) |
GC (column ZB-5, Silanization) |
MS-Q |
-/ 22-1232/ - |
4.27-0.21, 92 2.83-0.23, 100 10.1-0.87, 100 |
0.41-0.02 0.34-0.02, 89 7.33-0.08, 100 |
8 |