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Production of self-flow zero-cement castables based on matrix rheological control

Self-flow low-cement refractory castables have attracted much attention in the latest years because they combine the installation benefits of high-flowability castables with the good thermomechanical behaviour of low CaO-content refractories. By simultaneously controlling the castable particle size distribution and the matrix dispersion state, it becomes possible to eliminate the aluminous cement (CaO source) or any other hydraulic binder in the castable, keeping its self-flow ability. Such castables, named self-flow zero-cement castables, exhibit pre-firing mechanical strength compatible with industrial applications and outstanding high temperature properties. The matrix dispersion conditions necessary to obtain these castables are presented in this work. The optimum range of pH and dispersant amount for the matrix rheological optimisation are graphically presented in a stability map, which appears as a useful tool to prepare the self-flow high-alumina zero-cement castables.

alumina; dispersion; refractories; rheology; zero-cement


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