Surface Wettability Of Boron And Oil-Treated Wood

ABSTRACT

Background:

Nowadays, demands for more environmentally friendly and cost-effective preservatives are increasing, and new non-traditional procedures are being explored in wood protection field. Plant oils improve the dimensional stability, water repellency and equilibrium moisture content of wood, and protect wood against decay fungi by means of its hydrophobic properties. The aim of this study is to investigate the influence of heat treatment and oil impregnation with or without prior treatment with boron compounds on wetting characteristic of Scots pine ( Pinus sylvestris L.) and beech ( Fagus orientalis L.) wood. Wood specimens were impregnated with boric acid, borax and agricultural boron at concentrations of 1%, 2% and 5% followed by oil heat treated with waste and sunflower oil at 160ºC. Wettability was measured by contact angle with the sessile drop technique using water.

Results:

Water contact angles on oil treated specimens increased while wetting tension decreased, and the wood more poorly wetted by water compared to the controls. A change in the drop volume on the surface of double treated specimens was around 5% based on the initial drop volume. Waste oil treatment resulted in having the greatest water repellent efficiency. High loadings of boron compounds decreased the contact angle and therefore the quantity of water absorbed by the wood increased.

Conclusion:

Wettability was decreased in specimens pretreated with boron and this confirmed that the hydrophobic surface was created by oil. Wettability is a prerequisite for good adhesion, coating and painting and this feature may be reduced by the less hydrophilic surfaces created after oil heat treatment.

Keywords:
Boron compounds; contact angle; hydrophobicity; oil heat treatment; wood protection

HIGHLIGHTS

Waste oil treatment resulted in having the greatest water repellent efficiency.

Change in the drop volume was around 5% for wood surface treated with boron and oil.

Oil heat treatment improved surface hydrophobicity of boron treated specimens.

High loadings of boron compounds, especially TB and BX, decreased the contact angle.