Al-Harahsheh, M. S et al. (2015)AL-HARAHSHEH, M. S.; AL ZBOON, K.; AL-MAKHADMEH, L.; HARARAH, M.; MAHASNEH, M. Fly ash based geopolymer for heavy metal removal: a case study on copper removal. Journal of Environmental Chemical Engineering, v. 3, n. 3, p. 1669-1677, 2015. https://doi.org/10.1016/j.jece.2015.06.005 https://doi.org/10.1016/j.jece.2015.06.0...
|
Geopolímero à base de cinzas volantes |
Solução aquosa |
Cu2+
|
6,0 |
152,3 mg.g-1
|
|
Liu, Y. et al. (2016)LIU, Y.; YAN, C.; ZHANG, Z.; WANG, H.; ZHOU, S.; ZHOU, W. A comparative study on fly ash, geopolymer and faujasite block for Pb removal from aqueous solution. Fuel, v. 185, p. 181-189, 2016. https://doi.org/10.1016/j.fuel.2016.07.116 https://doi.org/10.1016/j.fuel.2016.07.1...
|
Geopolímero à base de cinzas volantes, cinzas volantes e bloco de faujasita |
Solução aquosa |
Pb2+
|
3,0 |
Geopolímero à base de cinzas volantes = 118,6 mg.g-1 Cinzas volantes = 49,8 mg.g-1 Bloco de faujasita = 143,3 mg.g-1
|
|
Luukkonen et al. (2016)LUUKKONEN, T.; RUNTTI, H.; NISKANEN, M.; TOLONEN, E.-T.; SARKKINEN, M.; KEMPPAINEN, K.; LASSI, U. Simultaneous removal of Ni(II), As(III), and Sb(III) from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers. Journal of environmental management, v. 166, p. 579-588, 2016. https://doi.org/10.1016/j.jenvman.2015.11.007 https://doi.org/10.1016/j.jenvman.2015.1...
|
Geopolímero de escória de alto forno |
DAM |
Ni2+ As3+ Sb3+
|
7,0-8,0 |
Ni = 4,42 mg.g-1 As = 0,52 mg.g-1 Sb = 0,34 mg.g-1
|
90–100% |
Kara, Yilmazer e Akar (2017)KARA, I.; YILMAZER, D.; AKAR, S. T. Metakaolin based geopolymer as an effective adsorbent for adsorption of zinc (ii) and nickel (ii) ions from aqueous solutions. Applied Clay Science, v. 139, p. 54-63, 2017. https://doi.org/10.1016/j.clay.2017.01.008 https://doi.org/10.1016/j.clay.2017.01.0...
|
Geopolímero à base de metacaulim |
Solução aquosa |
Zn2+ Ni2+
|
Zn = 6,39 Ni = 7,25 |
Zn = 1,14 10−3 mol.g-1 Ni = 7,26 10−4 mol.g-1
|
|
Jeremias, T.; Pineda-Vásques, T.; Lobo-Recio, M. (2018)JEREMIAS, T.; PINEDA-VÁSQUES, T.; LOBO-RECIO, M. Utilização de cinza da casca do arroz como biossorvente na remediação de águas fluviais impactadas por drenagem ácida mineral. In: Simpósio de Integração Científica e Tecnológica do Sul Catarinense – 7° SICT, Araranguá, 2018. Anais […]. Araranguá: Instituto Federal de Santa Catarina, 2018. Disponível em: http://eventoscientificos.ifsc.edu.br/index.php/sictsul/7-sict-sul/paper/view/2496. Acesso em: 20 out. 2019. http://eventoscientificos.ifsc.edu.br/in...
|
Cinza da casca de arroz |
Água fluvial com DAM |
Íons Fe, Al e Mn |
2,88–3,56 |
Aumento ~ 45% da concentração de Mn na solução |
Fe (> 98%) Al (~ 35%) |
Fontana, I.; Michael Peterson, M.; e Cechinel, M. (2018)FONTANA, I.; PETERSON, M.; CECHINEL, M. Application of brewing waste as biosorbent for the removal of metallic ions present in groundwater and surface waters from coal regions. Journal of Environmental Chemical Engineering, v. 6, n. 1, p. 660-670, 2018. http://doi.org/10.1016/j.jece.2018.01.005 http://doi.org/10.1016/j.jece.2018.01.00...
|
Resíduo da cerveja |
Solução aquosa com DAM |
Íons Fe e Mn |
5,3 |
Fe = 4 ± 1 mg.g-1 Mn = 0,96 ± 0,06 mg.g-1
|
Fe = 87% Mn = 71% |
Núñez-Gómez et al. (2019)NÚÑEZ-GÓMEZ, D.; RODRIGUES C.; LAPOLLI, F.; LOBO-RECIO, M. A. Adsorption of heavy metals from coal acid mine drainage by shrimp shell waste: isotherm and continuous-flow studies. Journal of Environmental Chemical Engineering, v. 7, n. 1, p. 102787, 2019. http://doi.org/10.1016/j.jece.2018.11.032 http://doi.org/10.1016/j.jece.2018.11.03...
|
Casca de camarão in natura
|
DAM |
Íons Fe e Mn |
3,49–6,77 |
Fe = 17, 43 mg.g-1 Mn = 3, 87 mg.g-1
|
Fe (até 90%) Mn (até 88%) |
Maleki et al. (2019)MALEKI, A.; HAJIZADEH, Z.; SHARIFI, V.; EMDADI, Z. A green, porous and eco-friendly magnetic geopolymer adsorbent for heavy metals removal from aqueous solutions. Journal of Cleaner Production, v. 215, p. 1233-1245, 2019. https://doi.org/10.1016/j.jclepro.2019.01.084 https://doi.org/10.1016/j.jclepro.2019.0...
|
Argila bentonita |
Águas residuais industriais |
Metais pesados como Cu, Pb, Ni, Cd e Hg |
7,0 |
|
Cu (99%) Pb (99%) Ni (92%) Cd (96%) Hg (92%) |
Yan et al. (2019)YAN, S.; HE, P.; JIA, D.; WANG, Q.; LIU, J.; YANG, J.; HUANG, Y. A green and low-cost hollow gangue microsphere/geopolymer adsorbent for the effective removal of heavy metals from wastewaters. Journal of Environmental Management, v. 246, p. 174-183, 2019. http://doi.org/10.1016/j.jenvman.2019.05.120 http://doi.org/10.1016/j.jenvman.2019.05...
|
Microesferas ocas de ganga |
Solução aquosa |
Cu2+ Cd2+ Zn2+ Pb2+
|
2,0–30 |
Cu2+ = 13,38 mg.g-1 Cd2+ = 10,83 mg.g-1 Zn2+ = 6,48 mg.g-1 Pb2+ = 61,4 mg.g-1
|
|
Ryu et al. (2020)RYU, S.; NAIDU, G.; MOON, H.; VIGNESWARAN, S. Selective copper recovery by membrane distillation and adsorption system from synthetic acid mine drainage. Chemosphere, v. 260, p. 127528, 2020. https://doi.org/10.1016/j.chemosphere.2020.127528 https://doi.org/10.1016/j.chemosphere.20...
|
Sílica mesoporosa modificada com Mn e enxerto de amina |
DAM sintética |
Cu2+
|
2,0–2,2 – 5,0–5,2 |
24,53 mg.g-1 para DAM tratada com KOH e 18,11 mg.g-1 para DAM tratada com NaOH |
|
Larazatou C. et al. (2020)LARAZATOU, C.; PANAGIOTARAS, D.; PANAGOPOULOS, G.; POSPÍŠIL, M.; PAPOULIS, D. Ca treated Palygorskite and Halloysite clay minerals for Ferrous Iron (Fe+2) removal from water systems. Environmental Technology & Innovation, v. 19, p. 10096, 2020. http://doi.org/10.1016/j.eti.2020.100961 http://doi.org/10.1016/j.eti.2020.100961...
|
Fibras de palygorskita e nanotubos de haloisita |
Solução aquosa |
Fe2+
|
Ca-Pal (4,0–6,0) Ca-Hall (pH > 8) |
|
Ca-Pal = 99,8% Ca-Hall = 91,2% |
Ngueagni et al. (2020)NGUEAGNI, P.; WOUMFO, E. D.; KUMAR, P. S.; SIÉWÉ, M.; VIEILLARD, J.; BRUN, N.; NKUIGUE, P. F. Adsorption of Cu(II) ions by modified horn core: effect of temperature on adsorbent preparation and extended application in river water. Journal of molecular liquids, v. 298, p. 112023, 2020. http://doi.org/10.1016/j.molliq.2019.112023 http://doi.org/10.1016/j.molliq.2019.112...
|
Núcleo do chifre do boi |
Água fluvial com metais |
Cu2+
|
4,12–4,64 |
99,98 mg.g-1
|
|
He et al. (2020)HE, X.; YAO, B.; XIA, Y.; HUANG, H.; GAN, Y.; ZHANG, W. Coal fly ash derived zeolite for highly efficient removal of Ni2+ inwaste water. Powder technology, v. 367, p. 40-46, 2020. https://doi.org/10.1016/j.powtec.2019.11.037 https://doi.org/10.1016/j.powtec.2019.11...
|
Zeólita tipo A derivada de cinzas volantes de carvão |
Águas residuais industriais |
Ni2+
|
7,0 |
47,0 mg.g-1
|
94% |
Sahoo et al. (2020)SAHOO, H.; SENAPATI, D.; THAKUR, I. S.; NAIK, U. C. Integrated bacteria-algal bioreactor for removal of toxic metals in acid mine drainage from iron ore mines. Bioresource Technology Reports, v. 11, p. 100422, 2020. http://doi.org/10.1016/j.biteb.2020.100422 http://doi.org/10.1016/j.biteb.2020.1004...
|
Bactérias e algas |
DAM |
Íons Fe, Al, Mn, Cu, Ti, Si e S |
4,3–7,0 |
|
95–99% |
Liu et al. (2021)LIU, J. REN, S.; CAO, J.; TSANG, D. C. W.; BEIYUAN, J.; PENG, Y.; WANG, J. Highly efficient removal of thallium in wastewater by MnFe2O4-biochar composite. Journal of Hazardous Materials, v. 401, p. 123311, 2021. http://doi.org/10.1016/j.jhazmat.2020.123311 http://doi.org/10.1016/j.jhazmat.2020.12...
|
MnFe2O4 –Biocarvão |
Águas residuais industriais |
TI (l) |
6,0 |
170,55 mg.g-1
|
49,61% |