1 |
mixture |
1.8 ± 0.1 |
nd
|
6.2-6.3 |
395, 421, 441, 465 |
nc
|
nd
|
nd
|
nd
|
2 |
(di-Z)-violaxanthin |
3.9 ± 0.2 |
nd
|
6.6 |
328, 409, 430, 455 |
15 |
30 |
601 |
nd
|
3 |
(9Z)-neoxanthin |
nd
|
15.2 ± 1.5 |
6.7 |
330, 415, 440, 469 |
84 |
24 |
601 |
583[M + H - 18]+, 565[M + H - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
4 |
(di-Z)-violaxanthin |
4.1 ± 0.1 |
nd
|
6.8-6.9 |
328, 408, 429, 456 |
35 |
32 |
601 |
nd
|
5 |
(all-E)-violaxanthin |
8.8 ± 0.5 |
66.9 ± 1.1 |
7.3-7.4 |
414, 438, 467 |
78 |
0 |
601 |
583[M + H - 18]+, 565[M + H - 18 - 18]+, 547[M + H - 18 - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
6 |
(all-E)-luteoxanthin |
5.1 ± 0.2 |
4.7 ± 0.2 |
8.5 |
400, 421, 447 |
93 |
0 |
601 |
583[M + H - 18] +, 565[M + H - 18 - 18] +, 547[M + H - 18 - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
7 |
not identified |
2.6 ± 0.01 |
nd
|
9.1 |
329, 402, 424, 445 |
19 |
27 |
601 |
583[M + H - 18]+, 565[M + H - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
8 |
(9Z)-violaxanthin + (all-E)-antheraxanthin |
30.3 ± 1.9 |
41.5 ± 1.3 |
10.4 |
328, 412, 435, 463 |
88 |
8 |
585, 601 |
[585]: 567[M + H - 18]+, 549[M + H - 18 - 18]+, 493[M + H - 92]+, 221; [601]: 583[M + H - 18]+, 565[M + H - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
9 |
(9Z) or (9'Z)-luteoxanthin |
2.3 ± 0.2 |
nd
|
10.8 |
310, 396, 417, 442 |
98 |
13 |
601 |
nd
|
10 |
(9Z) or (9'Z)-luteoxanthin |
5.5 ± 0.3 |
nd
|
11.4 |
310, 395, 417, 443 |
94 |
10 |
601 |
583[M + H - 18]+, 565[M + H - 18 - 18]+, 509[M + H - 92]+, 491[M + H - 92 - 18]+, 221 |
11 |
mutatoxanthin epimer |
2.1 ± 0.1 |
nd
|
12.0-12.1 |
400, 428, 449 |
70 |
0 |
585 |
567[M + H - 18]+, 549[M + H - 18 - 18]+, 493[M + H - 92]+, 221 |
12 |
(all-E)-lutein |
11.5 ± 0.7 |
nd
|
12.4 |
415, 444, 472 |
50 |
0 |
569 |
551[M + H - 18]+,533[M + H - 18 - 18]+, 477[M + H - 92]+
|
13 |
mutatoxanthin epimer |
1.3 ± 0.1 |
nd
|
13.0 |
402, 427, 451 |
63 |
0 |
585 |
567[M + H - 18]+, 549[M + H - 18 - 18]+, 493[M + H - 92]+, 221 |
14 |
(all-E)-zeaxanthin |
7.9 ± 0.5 |
nd
|
14.7 |
413, 450, 476 |
29 |
0 |
569 |
551[M + H - 18]+, 533[M + H - 18 - 18]+, 495[M + H - 56 - 18]+, 476[M - 92] +
|
15 |
(9Z)-antheraxanthin |
10.6 ± 0.7 |
nd
|
15.7 |
330, 410, 440, 468 |
60 |
9 |
585 |
567[M + H - 18]+, 549[M + H - 18 - 18]+, 493[M + H - 92]+, 475[M + H - 92 - 18]+, 221 |
16 |
(15Z) or (13Z)-zeinoxanthin + phytoene |
1.0 ± 0.02 |
nd
|
17.5 |
330, 412, 443, 467 |
16 |
51 |
553, 545 |
[553]: 535[M + H - 18]+, 461[M + H - 92]+; [545]: 489[M + H - 56]+
|
17 |
(all-E)-zeinoxanthin |
2.4 ± 0.1 |
nd
|
19.0-19.1 |
414, 445, 472 |
56 |
0 |
553 |
535[M + H - 18]+, 460[M - 92]+
|
18 |
(all-E)-β-cryptoxanthin |
4.2 ± 0.3 |
0.3 ± 0.04 |
22.5 |
415, 450, 477 |
26 |
0 |
553 |
535[M + H - 18]+, 461[M - H - 92]+
|
19 |
(13Z)-β-carotene |
nd
|
3.7 ± 0.002 |
27.8 |
338, 422, 445, 470 |
7 |
44 |
537 |
nd
|
20 |
(all-E)-α-carotene |
0.8 ± 0.07 |
nd
|
28.1 |
410, 445, 472 |
53 |
0 |
537 |
481[M + H - 56]+, 444[M - 92]+, 413, 401, 299, 281 |
21 |
(all-E)-β-carotene |
1.3 ± 0.1 |
43.3 ± 0.2 |
32.3 |
412, 451, 478 |
17 |
0 |
537 |
444[M - 92]+, 413 |
22 |
(9Z)-β-carotene |
nd
|
3.3 ± 0.2 |
34.5 |
339, 421, 447, 473 |
17 |
6 |
537 |
nd
|
|
Total carotenoids of freeze-dried pulp / (µg g-1) |
107 ± 5 |
180 ± 13 |
|
|
|
|
|
|
|
Total carotenoids of fresh pulp / (µg g-1) |
14.2 ± 0.7 |
25.2 ± 1.8 |
|
|
|
|
|
|