Goldschmidt11 Goldschmidt VM. Geochemische Verteilungsgesetze der Elemente VIII. Oslo: Skrifter Norske Videnkaps; 1926.
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1926 |
Tetrahedral configurations were necessary for the formation of a glass |
Oxides of the type AmOn
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Zachariasen22 Zachariasen WH. The atomic arrangement in glass. Journal of the American Chemical Society. 1932;54(10):3841-3851. DOI: 10.1021/ja01349a006 https://doi.org/10.1021/ja01349a006...
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1932 |
Continuous random network (CRN) |
SiO4
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Sun55 Sun KH. Fundamental condition of glass formation. Journal of the American Ceramic Society. 1947;30(9):277-281. DOI: 10.1111/j.1151-2916.1947.tb19654.x https://doi.org/10.1111/j.1151-2916.1947...
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1946 |
Model to obtain long range or network of atoms to form a glassy phase |
Oxides of the type M-O single bound |
Bernal, Mason33 Bernal JD, Mason J. Packing of spheres: coordination of randomly packed spheres. Nature. 1960;188(4754):910-911. DOI: 10.1038/188910a0 https://doi.org/10.1038/188910a0...
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1959 |
Model of dense random packing (DRP) or rigid spheres |
Bernal holes |
Polk66 Polk D. The structure of glassy metallic alloys. Acta Metallurgica. 1972;20(4):485-491. Doi: 10.1016/0001-6160(72)90003-X https://doi.org/10.1016/0001-6160(72)900...
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1972 |
Model to describe transition metal – metalloid glassy systems |
Metallic glasses |
Egami Waseda77 Egami T, Waseda YJ. Atomic size effect on the formability of metallic glasses. Journal of Non-Crystalline Solids. 1984;64(1-2):113-134.
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1984 |
Relation between glass formability and atomic size mismatch |
Binary metallic glassy alloys |
Granato88 Granato AV. Thermodynamic properties of liquid and amorphous monatomic metals from an interstitialcy model. Journal of Non-Crystalline Solids. 1993;156-158(Part 1):402-406. DOI: 10.1016/0022-3093(93)90206-D https://doi.org/10.1016/0022-3093(93)902...
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1993 |
The main roles of interstitial atoms is in destabilising the crystalline phase |
Frozen glassy and liquid states alloys |
Egami99 Egami T. Universal criterion for metallic glass formation. Materials Science and Engineering. 1997;226-228:261-267. doi:10.1016/S0921-5093(97)80041-X https://doi.org/10.1016/S0921-5093(97)80...
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1997 |
Topological instability applied to local atomic structure |
Metallic elements and alloys |
Senkov, Miracle1010 Senkov ON, Miracle DB. Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Materials Research Bulletin. 2001;36(12):2183-2198. DOI: 10.1016/S0025-5408(01)00715-2 https://doi.org/10.1016/S0025-5408(01)00...
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2001 |
Interstitial model for glass formation |
Prediction of glass formation |
Egami1111 Egami T. Atomistic mechanism of bulk metallic glass formation. Journal of Non-Crystalline Solids. 2003;317(1-2):30-33. doi:10.1016/S0022-3093(02)02003-3 https://doi.org/10.1016/S0022-3093(02)02...
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2003 |
Identified several conditions that would favour multicomponent bulk metallic glass formation |
Prediction of BMG-formation |
Miracle44 Miracle DB. A structural model for metallic glasses. Nature Materials. 2004;3:697-702. doi:10.1038/nmat1219 https://doi.org/10.1038/nmat1219...
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2004 |
Model to determine the alloy constituent concentration based on a topological atomistic approach |
Dense packing of atomic clusters for glass formation |