FASnI3 +PEABr |
ITO/PEDOT:PSS/PVSK/indene-C60bisadduct /BCP/Ag |
- |
0.91 |
20.60 |
77.10 |
14.63 |
One-step synthesis of SnI2.DMSO complex |
20212020 Jiang X, Li H, Zhou Q, Wei Q, Wei M, Jiang L, et al. One-step synthesis of SnI2·(DMSO)x adducts for high-performance tin perovskite solar cells. J Am Chem Soc. 2021;143(29):10970-6. http://dx.doi.org/10.1021/jacs.1c03032. PMid:34196528. http://dx.doi.org/10.1021/jacs.1c03032...
|
FASnI3 +PEABr |
ITO/PEDOT:PSS/PVSK/indene-C60bisadduct/BCP/Ag |
- |
0.96 |
16.70 |
76.40 |
12.20 |
Two step synthesis of SnI2. DMSO complex and removal of Sn4+ impurity |
20212020 Jiang X, Li H, Zhou Q, Wei Q, Wei M, Jiang L, et al. One-step synthesis of SnI2·(DMSO)x adducts for high-performance tin perovskite solar cells. J Am Chem Soc. 2021;143(29):10970-6. http://dx.doi.org/10.1021/jacs.1c03032. PMid:34196528. http://dx.doi.org/10.1021/jacs.1c03032...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.37 |
0.63 |
21.62 |
75.50 |
10.30 |
Vacuum treatment |
2021141141 Wan ZX, Ren SQ, Lai HG, Jiang Y, Wu X, Luo J, et al. Suppression of nonradiative recombination by vacuum-assisted process for efficient lead-free tin perovskite solar cells. Adv Mater Interfaces. 2021;8(9):2100135. http://dx.doi.org/10.1002/admi.202100135. http://dx.doi.org/10.1002/admi.202100135...
|
CsSnI3
|
ITO/PEDOT:PSS/PVSK/indene-C60 disadduct/BCP/Ag |
1.31 |
0.64 |
21.81 |
72.10 |
10.10 |
Localized electron engineering via phthalimide additive and indene-C60 disadduct for band alignment |
2021190190 Ye T, Wang X, Wang K, Ma S, Yang D, Hou Y, et al. Localized electron density engineering for stabilized B-γ CsSnI3-based perovskite solar cells with efficiencies >10%. ACS Energy Lett. 2021;6(4):1480-9. http://dx.doi.org/10.1021/acsenergylett.1c00342. http://dx.doi.org/10.1021/acsenergylett....
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.31 |
0.58 |
21.93 |
72.81 |
9.26 |
Hydrazine dihydrochloride additive |
2021165165 You J, Wang M, Xu C, Yao Y, Zhao X, Liu D, et al. Hydrazine dihydrochloride as a new additive to promote the performance of tin-based mixed organic cation perovskite solar cells. Sustain Energy Fuels. 2021;5(10):2660-7. http://dx.doi.org/10.1039/D1SE00160D. http://dx.doi.org/10.1039/D1SE00160D...
|
FASnI3
|
ITO/PEDOT:PSS/PSVK/C60/BCP/Ag |
1.40 |
0.53 |
21.80 |
65.80 |
7.53 |
Polyethylene glycol scafford |
2021125125 Chang B, Li B, Pan L, Li H, Wang L, Fu L, et al. Polyethylene glycol polymer scaffold induced intermolecular interactions for crystallization regulation and defect passivation in FASnI3 films. ACS Appl Energy Mater. 2021;4(4):3622-32. http://dx.doi.org/10.1021/acsaem.1c00009. http://dx.doi.org/10.1021/acsaem.1c00009...
|
CsSnI3
|
FTO/c-TiO2/m-TiO2/PVSK/P3HT/Au |
1.30 |
0.45 |
24.85 |
67.00 |
7.50 |
N,N′-methylenebis(acrylamide) (MBAA) additive and P3HT transport material |
2021191191 Ye T, Wang K, Hou Y, Yang D, Smith N, Magill B, et al. Ambient-air-stable lead-free cssni3 solar cells with greater than 7.5% efficiency. J Am Chem Soc. 2021;143(11):4319-28. http://dx.doi.org/10.1021/jacs.0c13069. PMid:33705120. http://dx.doi.org/10.1021/jacs.0c13069...
|
CsSnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.30 |
0.45 |
22.07 |
71.00 |
7.06 |
N,N′-methylenebis(acrylamide) (MBAA) additive and Spiro-OMeTAD |
2021191191 Ye T, Wang K, Hou Y, Yang D, Smith N, Magill B, et al. Ambient-air-stable lead-free cssni3 solar cells with greater than 7.5% efficiency. J Am Chem Soc. 2021;143(11):4319-28. http://dx.doi.org/10.1021/jacs.0c13069. PMid:33705120. http://dx.doi.org/10.1021/jacs.0c13069...
|
FA0.75MA0.25SnI2Br |
ITO/PEDOT:PSS/PVSK/PC61BM/BPhen/ Ag |
- |
0.56 |
16.66 |
65.00 |
6.02 |
Catechin antioxidant/dopant |
2021168168 Yang W-F, Cao J-J, Dong C, Li M, Tian Q-S, Wang Z-K, et al. Suppressed oxidation of tin perovskite by Catechin for eco-friendly indoor photovoltaics. Appl Phys Lett. 2021;118(2):23501. http://dx.doi.org/10.1063/5.0032951. http://dx.doi.org/10.1063/5.0032951...
|
GeI2 doped (FA0.90EA0.1)0.98EDA0.01SnI3
|
FTO/PEDOT:PSS/PVSK/C60/BCP/Ag/Au |
1.42 |
0.84 |
20.32 |
78.00 |
13.24 |
EDA surface passivation,bandgap alignment via EA doping and GeO4 protective layer |
2020131131 Nishimura K, Kamarudin MA, Hirotani D, Hamada K, Shen Q, Iikubo S, et al. Lead-free tin-halide perovskite solar cells with 13% efficiency. Nano Energy. 2020;74:104858. http://dx.doi.org/10.1016/j.nanoen.2020.104858. http://dx.doi.org/10.1016/j.nanoen.2020....
|
PEAxFA1−xSnI3
|
ITO/PEDOT:PSS/PVSK/indene-C60 disadduct/BCP/Ag |
1.39 |
0.94 |
17.40 |
75.00 |
12.40 |
NH4SCN additive, PEA(15%)/FA combination and indene-C60 disadduct electron transport material |
2020100100 Jiang X, Wang F, Wei Q, Li H, Shang Y, Zhou W, et al. Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design. Nat Commun. 2020;11(1):1245. http://dx.doi.org/10.1038/s41467-020-15078-2. PMid:32144245. http://dx.doi.org/10.1038/s41467-020-150...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT: PSS/PVSK/C60/BCP/Ag |
1.36 |
0.76 |
22.00 |
69.00 |
11.50 |
Sn nanoparticle in precursor solution, surface treatment with EDA and PC61BM |
2020155155 Nakamura T, Yakumaru S, Truong MA, Kim K, Liu J, Hu S, et al. Sn(IV)-free tin perovskite films realized by in situ Sn(0) nanoparticle treatment of the precursor solution. Nat Commun. 2020;11(1):3008. http://dx.doi.org/10.1038/s41467-020-16726-3. PMid:32546736. http://dx.doi.org/10.1038/s41467-020-167...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.40 |
0.76 |
23.50 |
64.00 |
11.40 |
Phenylhydrazine hydrochloride additive, SnF2 additive |
2020167167 Wang C, Gu F, Zhao Z, Rao H, Qiu Y, Cai Z, et al. Self-repairing tin-based perovskite solar cells with a breakthrough efficiency over 11%. Adv Mater. 2020;32(31):1907623. http://dx.doi.org/10.1002/adma.201907623. PMid:32583926. http://dx.doi.org/10.1002/adma.201907623...
|
FASnI3
|
ITO/PEDOT:PSS/ PSVK /C60/BCP/Ag |
- |
0.70 |
19.59 |
73.30 |
11.22 |
n-propylammonium iodide film |
2020128128 Liu X, Wu T, Chen J-Y, Meng X, He X, Noda T, et al. Templated growth of FASnI3 crystals for efficient tin perovskite solar cells. Energy Environ Sci. 2020;13(9):2896-902. http://dx.doi.org/10.1039/D0EE01845G. http://dx.doi.org/10.1039/D0EE01845G...
|
FASnI3
|
FTO/Cu-NiOx/PVSK/PCBM/BCP/Ag |
1.43 |
0.69 |
21.15 |
74.00 |
10.90 |
4-(aminomethyl)piperidinium (4AMP) additive |
2020183183 Chen M, Dong Q, Eickemeyer FT, Liu Y, Dai Z, Carl AD, et al. High-performance lead-free solar cells based on tin-halide perovskite thin films functionalized by a divalent organic cation. ACS Energy Lett. 2020;5(7):2223-30. http://dx.doi.org/10.1021/acsenergylett.0c00888. http://dx.doi.org/10.1021/acsenergylett....
|
FASnI3
|
ITO/PEDOT:PSS/ PSVK /C60/BCP/Ag |
- |
0.67 |
21.59 |
75.00 |
10.81 |
Pentafluorophen-oxyethylammonium iodide additive |
2020127127 Meng X, Wang Y, Lin J, Liu X, He X, Barbaud J, et al. Surface-controlled oriented growth of fasni3 crystals for efficient lead-free perovskite solar cells. Joule. 2020;4(4):902-12. http://dx.doi.org/10.1016/j.joule.2020.03.007. http://dx.doi.org/10.1016/j.joule.2020.0...
|
CsFASnI3
|
FTO/PEDOT:PSS/PSVK/PCBM/BCP/Ag |
1.39 |
0.64 |
21.60 |
75.20 |
10.40 |
Triple (I, Cl and I) halide amorphous system and CsFASnI3 polycrystals |
2020188188 Liu X, Wang Y, Wu T, He X, Meng X, Barbaud J, et al. Efficient and stable tin perovskite solar cells enabled by amorphous-polycrystalline structure. Nat Commun. 2020;11(1):2678. http://dx.doi.org/10.1038/s41467-020-16561-6. PMid:32472006. http://dx.doi.org/10.1038/s41467-020-165...
|
FASnI3
|
ITO/PEDOT:PSS/ PSVK /C60/BCP/Ag |
1.41 |
0.69 |
21.53 |
68.46 |
10.17 |
2-fluoro-phenethylammonium iodide |
2020123123 Li P, Dong H, Xu J, Chen J, Jiao B, Hou X, et al. Ligand orientation-induced lattice robustness for highly efficient and stable tin-based perovskite solar cells. ACS Energy Lett. 2020;5(7):2327-34. http://dx.doi.org/10.1021/acsenergylett.0c00960. http://dx.doi.org/10.1021/acsenergylett....
|
GeI2 doped FA0.98EDA0.01SnI3
|
FTO/PEDOT:PSS/PVSK/C60/BCP/Ag/Au |
1.39 |
0.54 |
23.15 |
72.00 |
9.03 |
GeI2 doping (GeO4 protective layer) and EDA doping |
2020131131 Nishimura K, Kamarudin MA, Hirotani D, Hamada K, Shen Q, Iikubo S, et al. Lead-free tin-halide perovskite solar cells with 13% efficiency. Nano Energy. 2020;74:104858. http://dx.doi.org/10.1016/j.nanoen.2020.104858. http://dx.doi.org/10.1016/j.nanoen.2020....
|
FASnI3
|
ITO/PEDOT:PSS/PSVK/C60/BCP/Ag |
- |
0.60 |
19.75 |
69.10 |
8.13 |
Phenylethylammonium iodide additive |
2020127127 Meng X, Wang Y, Lin J, Liu X, He X, Barbaud J, et al. Surface-controlled oriented growth of fasni3 crystals for efficient lead-free perovskite solar cells. Joule. 2020;4(4):902-12. http://dx.doi.org/10.1016/j.joule.2020.03.007. http://dx.doi.org/10.1016/j.joule.2020.0...
|
MASnI3
|
ITO/PEDOT:PSS/MASnI3/PC61BM/BCP/ Ag |
- |
0.57 |
20.68 |
66.00 |
7.78 |
Perovskite synthesis by ion exchange reaction between SnF2 and CH3NH3I Reaction time |
2020108108 Wang P, Li F, Jiang K-J, Zhang Y, Fan H, Zhang Y, et al. Ion exchange/insertion reactions for fabrication of efficient methylammonium tin iodide perovskite solar cells. Adv Sci. 2020;7(9):1903047. http://dx.doi.org/10.1002/advs.201903047. PMid:32382478. http://dx.doi.org/10.1002/advs.201903047...
|
FASnI3
|
ITO/PEDOT:PSS/ PSVK /C60/BCP/Ag |
- |
0.52 |
22.80 |
64.69 |
7.72 |
Poly(ethylene-co-vinyl acetate additive |
2020126126 Liu G, Liu C, Lin Z, Yang J, Huang Z, Tan L, et al. Regulated crystallization of efficient and stable tin-based perovskite solar cells via a self-sealing polymer. ACS Appl Mater Interfaces. 2020;12(12):14049-56. http://dx.doi.org/10.1021/acsami.0c01311. PMid:32129060. http://dx.doi.org/10.1021/acsami.0c01311...
|
FASnI3
|
ITO/PEDOT:PSS/PSVK /C60/BCP/Ag |
- |
0.54 |
19.41 |
66.40 |
6.93 |
Anti-solvent dripping |
2020127127 Meng X, Wang Y, Lin J, Liu X, He X, Barbaud J, et al. Surface-controlled oriented growth of fasni3 crystals for efficient lead-free perovskite solar cells. Joule. 2020;4(4):902-12. http://dx.doi.org/10.1016/j.joule.2020.03.007. http://dx.doi.org/10.1016/j.joule.2020.0...
|
FASnI3
|
ITO/PEDOT: PSS/PVSK/C60/BCP/Ag |
- |
0.53 |
17.37 |
73.47 |
6.80 |
Ethylenediammonium dihypophosphite additive and co-solvent (hexafluoro-2-propanol (HFP), isopropyl alcohol (IPA), and chlorobenzene) |
2020137137 Shahbazi S, Li M-Y, Fathi A, Diau EW-G. Realizing a cosolvent system for stable tin-based perovskite solar cells using a two-step deposition approach. ACS Energy Lett. 2020;5(8):2508-11. http://dx.doi.org/10.1021/acsenergylett.0c01190. http://dx.doi.org/10.1021/acsenergylett....
|
DPPA0.02FA0.98SnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
- |
0.48 |
21.73 |
65.34 |
6.75 |
3,3-diphenylpropylammonium (DPPA) doping |
2020180180 Xu X, Cao K, Zhu W, Gu W, Ma B, Qin M, et al. Improved crystallization and stability of mixed-cation tin iodide for lead-free perovskite solar cells. ACS Appl Energy Mater. 2020;3(6):5415-26. http://dx.doi.org/10.1021/acsaem.0c00407. http://dx.doi.org/10.1021/acsaem.0c00407...
|
(CsGA)0.15FA0.70SnI3with 1.5% EDAI2
|
ITO/PEDOT:PSS/PVSK/PC60BM/BCP/Ag |
- |
0.36 |
21.16 |
75.00 |
5.69 |
Cs, GA, FA combination and EDAI2 additive |
2020169169 Tosado GA, Zheng E, Yu Q. Tuning cesium–guanidinium in formamidinium tin triiodide perovskites with an ethylenediammonium additive for efficient and stable lead-free perovskite solar cells. Mater Adv. 2020;1(9):3507-17. http://dx.doi.org/10.1039/D0MA00520G. http://dx.doi.org/10.1039/D0MA00520G...
|
FASnI3
|
ITO/Nb2O5/PVSK/PTAA/Au |
- |
0.42 |
22.80 |
52.00 |
5.10 |
Nb2O5 transport electron layer |
20209191 Yokoyama T, Nishitani Y, Miyamoto Y, Kusumoto S, Uchida R, Matsui T, et al. Improving the open-circuit voltage of Sn-based perovskite solar cells by band alignment at the electron transport layer/perovskite layer interface. ACS Appl Mater Interfaces. 2020;12(24):27131-9. http://dx.doi.org/10.1021/acsami.0c04676. PMid:32427458. http://dx.doi.org/10.1021/acsami.0c04676...
|
PEA0.1FA0.9SnI(SCN)2 + 5% EDAI2
|
ITO/c-TiO2/m-TiO2/Al2O3/NiOx/PVSK/ Carbon |
- |
0.33 |
20.17 |
57.40 |
3.70 |
PEAI (10%) doping, EDAI2 (5%) additive and Thiocynate (SCN-) doping |
20207575 Rameez M, Lin EY-R, Raghunath P, Narra S, Song D, Lin MC, et al. Development of hybrid pseudohalide tin perovskites for highly stable carbon-electrode solar cells. ACS Appl Mater Interfaces. 2020;12(19):21739-47. http://dx.doi.org/10.1021/acsami.0c03704. PMid:32295339. http://dx.doi.org/10.1021/acsami.0c03704...
|
FASnI(SCN)2
|
ITO/c-TiO/m-TiO2/Al2O3/PVSK/Carbon |
1.38 |
0.27 |
16.04 |
54.9 |
2.40 |
Thiocynate (SCN-) doping |
20207575 Rameez M, Lin EY-R, Raghunath P, Narra S, Song D, Lin MC, et al. Development of hybrid pseudohalide tin perovskites for highly stable carbon-electrode solar cells. ACS Appl Mater Interfaces. 2020;12(19):21739-47. http://dx.doi.org/10.1021/acsami.0c03704. PMid:32295339. http://dx.doi.org/10.1021/acsami.0c03704...
|
Cs0.05(FA0.83MA0.17)0.95Pb0.5Sn0.5I3
|
ITO/PEDOT:PSS/PVSK/PC60BM/Al doped Zn/BCP/Ag |
1.27 |
0.62 |
27.59 |
61.00 |
11.60 |
Toluene antisolvent and thermal treatment |
2019177177 Bandara RMI, Jayawardena KDGI, Adeyemo SO, Hinder SJ, Smith JA, Thirimanne HM, et al. Tin(IV) dopant removal through anti-solvent engineering enabling tin based perovskite solar cells with high charge carrier mobilities. J Mater Chem C Mater Opt Electron Devices. 2019;7(27):8389-97. http://dx.doi.org/10.1039/C9TC02003A. http://dx.doi.org/10.1039/C9TC02003A...
|
FASnI3
|
ITO/PEDOT:PSS/ PSVK/C60/BCP/Ag |
1.37 |
0.63 |
20.37 |
69.30 |
8.92 |
Poly(vinyl alcohol) additive |
2019124124 Meng X, Lin J, Liu X, He X, Wang Y, Noda T, et al. Highly stable and efficient fasni3-based perovskite solar cells by introducing hydrogen bonding. Adv Mater. 2019;31(42):1903721. http://dx.doi.org/10.1002/adma.201903721. PMid:31495977. http://dx.doi.org/10.1002/adma.201903721...
|
FA0.98EDA0.01SnI3
|
FTO/PEDOT:PSS/PVSK/C60/BCP/Ag/Au |
1.38 |
0.49 |
24.08 |
75.00 |
8.90 |
1,2-diaminoethane passivation |
2019130130 Kamarudin MA, Hirotani D, Wang Z, Hamada K, Nishimura K, Shen Q, et al. Suppression of charge carrier recombination in lead-free tin halide perovskite via lewis base post-treatment. J Phys Chem Lett. 2019;10(17):5277-83. http://dx.doi.org/10.1021/acs.jpclett.9b02024. PMid:31423786. http://dx.doi.org/10.1021/acs.jpclett.9b...
|
GAxFA1−x−2ySnI3–yEDAI2
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.50 |
0.56 |
20.80 |
72.60 |
8.50 |
GA/FA combination and EDAI2 additive |
2019192192 Jokar E, Chien C-H, Tsai C-M, Fathi A, Diau EW-G. Robust tin-based perovskite solar cells with hybrid organic cations to attain efficiency approaching 10%. Adv Mater. 2019;31(2):1804835. http://dx.doi.org/10.1002/adma.201804835. PMid:30411826. http://dx.doi.org/10.1002/adma.201804835...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/BCP/Ag |
- |
0.54 |
22.12 |
71.00 |
8.48 |
Trihydrazine dihydriodide additive |
2019166166 Li F, Fan H, Zhang J, Huang J-H, Wang P, Gao C, et al. Trihydrazine dihydriodide-assisted fabrication of efficient formamidinium tin iodide perovskite solar cells. Sol RRL. 2019;3(9):1900285. http://dx.doi.org/10.1002/solr.201900285. http://dx.doi.org/10.1002/solr.201900285...
|
{en}FASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/BDT-4D/Au |
- |
0.50 |
22.41 |
68.21 |
7.59 |
Tetra- 4,4'-dimethoxy triphenylamine-substituted benzodithiophene hole transport material |
20199090 Vegiraju S, Ke W, Priyanka P, Ni J-S, Wu Y-C, Spanopoulos I, et al. Benzodithiophene hole-transporting materials for efficient tin-based perovskite solar cells. Adv Funct Mater. 2019;29(45):1905393. http://dx.doi.org/10.1002/adfm.201905393. http://dx.doi.org/10.1002/adfm.201905393...
|
{en}FASnI3
|
FTO/SnO2-CPTA/PVSK/PTAA/Au |
- |
0.69 |
16.45 |
65.00 |
7.40 |
SnO2-C60pyrrolidine tris-acid electron transport layer |
20199393 Yang Z, Zhong M, Liang Y, Yang L, Liu X, Li Q, et al. SnO2-C60 pyrrolidine tris-acid (CPTA) as the electron transport layer for highly efficient and stable planar Sn-based perovskite solar cells. Adv Funct Mater. 2019;29(42):1903621. http://dx.doi.org/10.1002/adfm.201903621. http://dx.doi.org/10.1002/adfm.201903621...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/PTN-Br/C60/BCP/Ag |
1.35 |
0.57 |
20.66 |
67.40 |
7.38 |
PTN-Br/perovskite heterojunction, Band alignment and passivation |
20199797 Liu C, Tu J, Hu X, Huang Z, Meng X, Yang J, et al. Enhanced hole transportation for inverted tin-based perovskite solar cells with high performance and stability. Adv Funct Mater. 2019;29(18):1808059. http://dx.doi.org/10.1002/adfm.201808059. http://dx.doi.org/10.1002/adfm.201808059...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/MASnI3/PTAA/Au |
- |
0.49 |
22.91 |
64.00 |
7.12 |
NH2NH3SnI3derived perovskite and two step method |
2019163163 Li F, Zhang C, Huang J-H, Fan H, Wang H, Wang P, et al. A cation-exchange approach for the fabrication of efficient methylammonium tin iodide perovskite solar cells. Angew Chem Int Ed. 2019;58(20):6688-92. http://dx.doi.org/10.1002/anie.201902418. PMid:30884017. http://dx.doi.org/10.1002/anie.201902418...
|
FASnI3
|
ITO/PEDOT: PSS/PVSK/C60/BCP/PEI/Ag |
- |
0.53 |
19.59 |
61.00 |
6.33 |
Post-deposition vapor annealing with MACl2
|
2019139139 Chowdhury TH, Kayesh ME, Lee J-J, Matsushita Y, Kazaoui S, Islam A. Post-deposition vapor annealing enables fabrication of 1 cm2 lead-free perovskite solar cells. Sol RRL. 2019;3(12):1900245. http://dx.doi.org/10.1002/solr.201900245. http://dx.doi.org/10.1002/solr.201900245...
|
CsSnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/Ag |
- |
- |
- |
- |
5.03 |
Quantum dots and triphenyl phosphite antioxidant solvent |
2019133133 Wang Y, Tu J, Li T, Tao C, Deng X, Li Z. Convenient preparation of CsSnI3 quantum dots, excellent stability,and the highest performance of lead-free inorganic perovskite solar cells so far. J Mater Chem A Mater Energy Sustain. 2019;7(13):7683-90. http://dx.doi.org/10.1039/C8TA10901J. http://dx.doi.org/10.1039/C8TA10901J...
|
FA0.75MA0.25SnI3
|
FTO/c-TiO2/PVSK/PTAA/Au |
1.33 |
0.26 |
17.40 |
42.00 |
1.85 |
Gas pump treatment |
2019122122 Li X-L, Gao L-L, Chu Q-Q, Li Y, Ding B, Yang G-J. Green solution-processed tin-based perovskite films for lead-free planar photovoltaic devices. ACS Appl Mater Interfaces. 2019;11(3):3053-60. http://dx.doi.org/10.1021/acsami.8b19143. PMid:30585479. http://dx.doi.org/10.1021/acsami.8b19143...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/ PSVK/C60/BCP/Al |
1.31 |
0.55 |
24.30 |
67.30 |
9.06 |
Chlorobenzene antisolvent dripping plus SnF2
|
2018111111 Liu X, Yan K, Tan D, Liang X, Zhang H, Huang W. Solvent engineering improves efficiency of lead-free tin-based hybrid perovskite solar cells beyond 9%. ACS Energy Lett. 2018;3(11):2701-7. http://dx.doi.org/10.1021/acsenergylett.8b01588. http://dx.doi.org/10.1021/acsenergylett....
|
FASnI3
|
ITO/PEDOT:PSS/PSVK/C60/BCP/Ag |
1.43 |
0.58 |
21.30 |
71.80 |
8.90 |
Ethylenediammonium diiodide additive |
2018129129 Jokar E, Chien C-H, Fathi A, Rameez M, Chang Y-H, Diau EW-G. Slow surface passivation and crystal relaxation with additives to improve device performance and durability for tin-based perovskite solar cells. Energy Environ Sci. 2018;11(9):2353-62. http://dx.doi.org/10.1039/C8EE00956B. http://dx.doi.org/10.1039/C8EE00956B...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/ PSVK/C60/BCP/Al |
1.31 |
0.52 |
22.70 |
62.70 |
7.52 |
Toluene antisolvent dripping plus SnF2
|
2018111111 Liu X, Yan K, Tan D, Liang X, Zhang H, Huang W. Solvent engineering improves efficiency of lead-free tin-based hybrid perovskite solar cells beyond 9%. ACS Energy Lett. 2018;3(11):2701-7. http://dx.doi.org/10.1021/acsenergylett.8b01588. http://dx.doi.org/10.1021/acsenergylett....
|
(PEA,FA)SnI3
|
ITO/LiF/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.37 |
0.47 |
20.07 |
74.00 |
6.98 |
LiF layer and 2D-3D heterojunction |
20189898 Ran C, Xi J, Gao W, Yuan F, Lei T, Jiao B, et al. Bilateral interface engineering toward efficient 2D-3D bulk heterojunction tin halide lead-free perovskite solar cells. ACS Energy Lett. 2018;3(3):713-21. http://dx.doi.org/10.1021/acsenergylett.8b00085. http://dx.doi.org/10.1021/acsenergylett....
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
- |
0.58 |
17.50 |
66.30 |
6.75 |
Purification of tin precursor using Sn metal and SnF2 additive |
2018159159 Gu F, Ye S, Zhao Z, Rao H, Liu Z, Bian Z, et al. Improving performance of lead-free formamidinium tin triiodide perovskite solar cells by tin source purification. Sol RRL. 2018;2(10):1800136. http://dx.doi.org/10.1002/solr.201800136. http://dx.doi.org/10.1002/solr.201800136...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/ PSVK /C60/BCP/Al |
1.31 |
0.49 |
23.70 |
55.30 |
6.39 |
Diethyl ether antisolvent dripping plus SnF2
|
2018111111 Liu X, Yan K, Tan D, Liang X, Zhang H, Huang W. Solvent engineering improves efficiency of lead-free tin-based hybrid perovskite solar cells beyond 9%. ACS Energy Lett. 2018;3(11):2701-7. http://dx.doi.org/10.1021/acsenergylett.8b01588. http://dx.doi.org/10.1021/acsenergylett....
|
CsxFA1–xSnI3
|
ITO/PEDOT: PSS/PVSK/C60/BCP/Ag |
- |
0.44 |
20.70 |
66.70 |
6.08 |
Cs doping |
20186262 Gao W, Ran C, Li J, Dong H, Jiao B, Zhang L, et al. Robust stability of efficient lead-free formamidinium tin iodide perovskite solar cells realized by structural regulation. J Phys Chem Lett. 2018;9(24):6999-7006. http://dx.doi.org/10.1021/acs.jpclett.8b03194. PMid:30499301. http://dx.doi.org/10.1021/acs.jpclett.8b...
|
FASnI3
|
ITO/PEDOT: PSS/PVSK/PCBM/PEI/Al |
- |
0.54 |
17.03 |
66.00 |
6.03 |
Pb(SCN)2 additive and vacuum-assisted annealing |
2018140140 Gao F, Li C, Qin L, Zhu L, Huang X, Liu H, et al. Enhanced performance of tin halide perovskite solar cell by addition of lead thiocyanate. RSC Advances. 2018;8(25):14025-30. http://dx.doi.org/10.1039/C8RA00809D. http://dx.doi.org/10.1039/C8RA00809D...
|
FASnI3
|
ITO/PEDOT:PSS/PSVK/C60/BCP/Ag |
1.43 |
0.44 |
18.00 |
69.40 |
5.50 |
n-Butylammonium iodide additive |
2018129129 Jokar E, Chien C-H, Fathi A, Rameez M, Chang Y-H, Diau EW-G. Slow surface passivation and crystal relaxation with additives to improve device performance and durability for tin-based perovskite solar cells. Energy Environ Sci. 2018;11(9):2353-62. http://dx.doi.org/10.1039/C8EE00956B. http://dx.doi.org/10.1039/C8EE00956B...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/BCP/Ag |
- |
0.46 |
17.64 |
67.00 |
5.40 |
Hydrazinium chloride additive and SnF2
|
2018164164 Kayesh ME, Chowdhury TH, Matsuishi K, Kaneko R, Kazaoui S, Lee J-J, et al. Enhanced photovoltaic performance of FASnI3-based perovskite solar cells with hydrazinium chloride coadditive. ACS Energy Lett. 2018;3(7):1584-9. http://dx.doi.org/10.1021/acsenergylett.8b00645. http://dx.doi.org/10.1021/acsenergylett....
|
MASnCI3
|
FTO/c-TiO2/PVSK/CuSCN/Ag |
1.30 |
0.58 |
12.89 |
55.00 |
3.41 |
Annealing temperature |
20187474 Moyez SA, Roy S. Thermal engineering of lead-free nanostructured CH3NH3SnCl3 perovskite material for thin-film solar cell. J Nanopart Res. 2017;20(1):5. http://dx.doi.org/10.1007/s11051-017-4108-z. http://dx.doi.org/10.1007/s11051-017-410...
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/C60/BCP/Ag/Au |
1.40 |
0.46 |
17.61 |
41.00 |
3.31 |
MA/FA balance |
20186767 Ito N, Kamarudin MA, Hirotani D, Zhang Y, Shen Q, Ogomi Y, et al. Mixed Sn–Ge perovskite for enhanced perovskite solar cell performance in air. J Phys Chem Lett. 2018;9(7):1682-8. http://dx.doi.org/10.1021/acs.jpclett.8b00275. PMid:29536736. http://dx.doi.org/10.1021/acs.jpclett.8b...
|
MA0.5FA0.5Pb0.5Sn0.5I3
|
ITO/PEDOT:PSS/PVSK/PCBM/bis-C60/Ag |
1.24 |
0.78 |
25.69 |
70.00 |
14.01 |
Ascorbic acid additive |
2017160160 Xu X, Chueh C-C, Yang Z, Rajagopal A, Xu J, Jo SB, et al. Ascorbic acid as an effective antioxidant additive to enhance the efficiency and stability of Pb/Sn-based binary perovskite solar cells. Nano Energy. 2017;34:392-8. http://dx.doi.org/10.1016/j.nanoen.2017.02.040. http://dx.doi.org/10.1016/j.nanoen.2017....
|
FA0.75MA0.25SnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/C60/BCP/ Ag |
1.33 |
0.61 |
21.20 |
62.7 |
8.12 |
Relation between MA and FA cation |
20175757 Zhao Z, Gu F, Li Y, Sun W, Ye S, Rao H, et al. Mixed-organic-cation tin iodide for lead-free perovskite solar cells with an efficiency of 8.12%. Adv Sci. 2017;4(11):1700204. http://dx.doi.org/10.1002/advs.201700204. PMid:29201617. http://dx.doi.org/10.1002/advs.201700204...
|
{en}FASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/TPE/Au |
- |
0.46 |
22.54 |
69.70 |
7.23 |
Tetrakis-triphenylamine hole transport material |
20178585 Ke W, Priyanka P, Vegiraju S, Stoumpos CC, Spanopoulos I, Soe CMM, et al. Dopant-free tetrakis-triphenylamine hole transporting material for efficient tin-based perovskite solar cells. J Am Chem Soc. 2018;140(1):388-93. http://dx.doi.org/10.1021/jacs.7b10898. PMid:29211458. http://dx.doi.org/10.1021/jacs.7b10898...
|
{en} FASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/PTAA/Au |
1.50 |
0.48 |
22.54 |
65.96 |
7.14 |
Ethylenediammonium incorporation |
20176161 Ke W, Stoumpos CC, Zhu M, Mao L, Spanopoulos I, Liu J, et al. Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI3. Sci Adv. 2017;3(8):e1701293. http://dx.doi.org/10.1126/sciadv.1701293. PMid:28875173. http://dx.doi.org/10.1126/sciadv.1701293...
|
FASnI3
|
ITO/PEDOT:PSS)/PVSK/C60:1 wt%/TBAI/Ag |
1.40 |
0.47 |
22.45 |
67.80 |
7.09 |
Trimethylamine complex, SnF2 additive, sequential deposition and inverted architecture |
2017136136 Zhu Z, Chueh C-C, Li N, Mao C, Jen AK-Y. Realizing efficient lead-free formamidinium tin triiodide perovskite solar cells via a sequential deposition route. Adv Mater. 2018;30(6):1703800. http://dx.doi.org/10.1002/adma.201703800. PMid:29250846. http://dx.doi.org/10.1002/adma.201703800...
|
{en} MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/PTAA/Au |
1.40 |
0.43 |
24.28 |
63.72 |
6.63 |
Ethylenediammonium incorporation |
20176060 Ke W, Stoumpos CC, Spanopoulos I, Mao L, Chen M, Wasielewski MR, et al. Efficient lead-free solar cells based on hollow {en}MASnI3 perovskites. J Am Chem Soc. 2017;139(41):14800-6. http://dx.doi.org/10.1021/jacs.7b09018. PMid:28953381. http://dx.doi.org/10.1021/jacs.7b09018...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/C60/BCP/Ag |
1.36 |
0.48 |
21.3 |
64.60 |
6.60 |
FA cation |
20175757 Zhao Z, Gu F, Li Y, Sun W, Ye S, Rao H, et al. Mixed-organic-cation tin iodide for lead-free perovskite solar cells with an efficiency of 8.12%. Adv Sci. 2017;4(11):1700204. http://dx.doi.org/10.1002/advs.201700204. PMid:29201617. http://dx.doi.org/10.1002/advs.201700204...
|
(PEA)2(FA)8Sn9I28
|
ITO/NiOx/PVSK/PCBM/Al |
- |
0.59 |
14.44 |
69.00 |
5.94 |
Phenylethylammonium doping to form 2D layers |
2017181181 Liao Y, Liu H, Zhou W, Yang D, Shang Y, Shi Z, et al. Highly oriented low-dimensional tin halide perovskites with enhanced stability and photovoltaic performance. J Am Chem Soc. 2017;139(19):6693-9. http://dx.doi.org/10.1021/jacs.7b01815. PMid:28438016. http://dx.doi.org/10.1021/jacs.7b01815...
|
CsSnI3
|
FTO/c-TiO2/m-TiO2/PVSK/PTAA doped with TPFB/Au |
- |
0.38 |
25.71 |
49.05 |
4.81 |
CsI/SnI2 ratio, reducing atmosphere and excess SnI2
|
2017152152 Song T-B, Yokoyama T, Aramaki S, Kanatzidis MG. Performance enhancement of lead-free tin-based perovskite solar cells with reducing atmosphere-assisted dispersible additive. ACS Energy Lett. 2017;2(4):897-903. http://dx.doi.org/10.1021/acsenergylett.7b00171. http://dx.doi.org/10.1021/acsenergylett....
|
FASnI3
|
ITO/SnO2/C60/PVSK/Spiro /Ag |
1.40 |
0.31 |
21.65 |
64.70 |
4.34 |
Trimethylamine complex, SnF2 additive and sequential deposition |
2017136136 Zhu Z, Chueh C-C, Li N, Mao C, Jen AK-Y. Realizing efficient lead-free formamidinium tin triiodide perovskite solar cells via a sequential deposition route. Adv Mater. 2018;30(6):1703800. http://dx.doi.org/10.1002/adma.201703800. PMid:29250846. http://dx.doi.org/10.1002/adma.201703800...
|
MASnI3
|
ITO/PEDOT:PSS/PVSK/PCBM/C60/ BCP/Ag |
1.26 |
0.46 |
21.4 |
42.70 |
4.29 |
MA cation |
20175757 Zhao Z, Gu F, Li Y, Sun W, Ye S, Rao H, et al. Mixed-organic-cation tin iodide for lead-free perovskite solar cells with an efficiency of 8.12%. Adv Sci. 2017;4(11):1700204. http://dx.doi.org/10.1002/advs.201700204. PMid:29201617. http://dx.doi.org/10.1002/advs.201700204...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK//PTAA/Au |
1.30 |
0.37 |
19.92 |
51.73 |
3.89 |
Reducing hydrazine atmosphere |
2017161161 Song T-B, Yokoyama T, Stoumpos CC, Logsdon J, Cao DH, Wasielewski MR, et al. Importance of reducing vapor atmosphere in the fabrication of tin-based perovskite solar cells. J Am Chem Soc. 2017;139(2):836-42. http://dx.doi.org/10.1021/jacs.6b10734. PMid:27977193. http://dx.doi.org/10.1021/jacs.6b10734...
|
{en} CsSnI3
|
FTO/c-TiO2/m-TiO2/PVSK/PTAA/Au |
- |
0.28 |
25.07 |
53.82 |
3.79 |
Ethylenediammonium incorporation |
20176060 Ke W, Stoumpos CC, Spanopoulos I, Mao L, Chen M, Wasielewski MR, et al. Efficient lead-free solar cells based on hollow {en}MASnI3 perovskites. J Am Chem Soc. 2017;139(41):14800-6. http://dx.doi.org/10.1021/jacs.7b09018. PMid:28953381. http://dx.doi.org/10.1021/jacs.7b09018...
|
MASnIBr2
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
- |
0.45 |
13.77 |
59.58 |
3.70 |
SnF2 additive |
2017119119 Xiao M, Gu S, Zhu P, Tang M, Zhu W, Lin R, et al. Tin-based perovskite with improved coverage and crystallinity through tin-fluoride-assisted heterogeneous nucleation. Adv Opt Mater. 2018;6(1):1700615. http://dx.doi.org/10.1002/adom.201700615. http://dx.doi.org/10.1002/adom.201700615...
|
MASnBr0.5I2.5
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.40 |
0.18 |
15.44 |
38.00 |
1.05 |
Br doping and MeOH/Dioxane solution |
2017116116 Greul E, Docampo P, Bein T. Synthesis of hybrid tin halide perovskite solar cells with less hazardous solvents: methanol and 1,4-dioxane. Z Anorg Allg Chem. 2017;643(21):1704-11. http://dx.doi.org/10.1002/zaac.201700297. http://dx.doi.org/10.1002/zaac.201700297...
|
FA0.75Cs0.25Sn0.5Pb0.5I3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.20 |
0.74 |
26.70 |
71.00 |
14.10 |
Sn doping and Cs doping |
2016173173 Eperon GE, Leijtens T, Bush KA, Prasanna R, Green T, Wang JT-W, et al. Perovskite-perovskite tandem photovoltaics with optimized band gaps. Science. 2016;354(6314):861-5. http://dx.doi.org/10.1126/science.aaf9717. http://dx.doi.org/10.1126/science.aaf971...
|
MASn0.5Pb0.5I3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.18 |
0.75 |
26.30 |
68.80 |
13.60 |
Sn/Pb mixture and Pb two step method |
2016172172 Li Y, Sun W, Yan W, Ye S, Rao H, Peng H, et al. 50% Sn-based planar perovskite solar cell with power conversion efficiency up to 13.6%. Adv Energy Mater. 2016;6(24):1601353. http://dx.doi.org/10.1002/aenm.201601353. http://dx.doi.org/10.1002/aenm.201601353...
|
CsSnI3
|
ITO/TiO2 /PVSK/Spiro/Au |
- |
0.86 |
23.21 |
65.00 |
12.96 |
Quantum rods |
2016189189 Chen L-J, Lee C-R, Chuang Y-J, Wu Z-H, Chen C. Synthesis and optical properties of lead-free cesium tin halide perovskite quantum rods with high-performance solar cell application. J Phys Chem Lett. 2016;7(24):5028-35. http://dx.doi.org/10.1021/acs.jpclett.6b02344. PMid:27973874. http://dx.doi.org/10.1021/acs.jpclett.6b...
|
FASnI3
|
ITO/PEDOT:PSS/PVSK/C60/BCP/Ag |
1.40 |
0.47 |
22.07 |
60.67 |
6.22 |
Inverted cell architecture, SnF2 additive and solvent engineering |
20164949 Liao W, Zhao D, Yu Y, Grice CR, Wang C, Cimaroli AJ, et al. Lead-free inverted planar formamidinium tin triiodide perovskite solar cells achieving power conversion efficiencies up to 6.22%. Adv Mater. 2016;28(42):9333-40. http://dx.doi.org/10.1002/adma.201602992. PMid:27571446. http://dx.doi.org/10.1002/adma.201602992...
|
FASnI3
|
FTO/c-TiO2/m- TiO2/ZnS-/PVSK/PTAA/Au |
1.40 |
0.38 |
23.09 |
60.01 |
5.27 |
TiO2-ZnS electron transport material |
20169696 Ke W, Stoumpos CC, Logsdon JL, Wasielewski MR, Yan Y, Fang G, et al. TiO2-ZnS cascade electron transport layer for efficient formamidinium tin iodide perovskite solar cells. J Am Chem Soc. 2016;138(45):14998-5003. http://dx.doi.org/10.1021/jacs.6b08790. PMid:27776416. http://dx.doi.org/10.1021/jacs.6b08790...
|
FASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.40 |
0.32 |
23.70 |
63.00 |
4.80 |
SnF2–pyrazine complex |
2016109109 Lee SJ, Shin SS, Kim YC, Kim D, Ahn TK, Noh JH, et al. Fabrication of efficient formamidinium tin iodide perovskite solar cells through SnF2-pyrazine complex. J Am Chem Soc. 2016;138(12):3974-7. http://dx.doi.org/10.1021/jacs.6b00142. PMid:26960020. http://dx.doi.org/10.1021/jacs.6b00142...
|
CsSnI3
|
ITO/PVSK/PC61BM/BCP/Al |
- |
0.50 |
9.89 |
68.00 |
3.56 |
SnCl2 additive and no electron transport layer |
2016153153 Marshall KP, Walker M, Walton RI, Hatton RA. Enhanced stability and efficiency in hole-transport-layer-free CsSnI3 perovskite photovoltaics. Nat Energy. 2016;1(12):16178. http://dx.doi.org/10.1038/nenergy.2016.178. http://dx.doi.org/10.1038/nenergy.2016.1...
|
CsSnI3
|
ITO/NiOx/PVSK/PCBM/Al |
1.30 |
0.52 |
10.21 |
62.50 |
3.31 |
NiOx hole transport material and controlled grain coarsening |
2016146146 Wang N, Zhou Y, Ju M-G, Garces HF, Ding T, Pang S, et al. Heterojunction-depleted lead-free perovskite solar cells with coarse-grained B-γ-CsSnI3 thin films. Adv Energy Mater. 2016;6(24):1601130. http://dx.doi.org/10.1002/aenm.201601130. http://dx.doi.org/10.1002/aenm.201601130...
|
MASnI3
|
FTO/c-TiO/m-TiO2/PVSK/PTAA/Au |
1.26 |
0.27 |
17.80 |
39.00 |
1.86 |
Temperature controlled reaction of SnI2 film with MAI gas and use of 2,6-lutidine instead of tBP. |
20164848 Yokoyama T, Cao DH, Stoumpos CC, Song TB, Sato Y, Aramaki S, et al. Overcoming short-circuit in lead-free CH3NH3SnI3 perovskite solar cells via kinetically controlled gas–solid reaction film fabrication process. J Phys Chem Lett. 2016;7(5):776-82. http://dx.doi.org/10.1021/acs.jpclett.6b00118. PMid:26877089. http://dx.doi.org/10.1021/acs.jpclett.6b...
|
MASnI3
|
ITO/PEDOT:PSS/Poly-TPD/PVSK/C60/BCP/Ag |
1.30 |
0.38 |
12.10 |
36.60 |
1.70 |
Co-evaporation of precursors |
20169999 Yu Y, Zhao D, Grice CR, Meng W, Wang C, Liao W, et al. Thermally evaporated methylammonium tin triiodide thin films for lead-free perovskite solar cell fabrication. RSC Advances. 2016;6(93):90248-54. http://dx.doi.org/10.1039/C6RA19476A. http://dx.doi.org/10.1039/C6RA19476A...
|
CsSnI3
|
FTO/c-TiO2/PVSK/Spiro/Au |
1.30 |
0.48 |
8.11 |
19.80 |
0.77 |
Undoped Spiro-OMeTAD |
2016146146 Wang N, Zhou Y, Ju M-G, Garces HF, Ding T, Pang S, et al. Heterojunction-depleted lead-free perovskite solar cells with coarse-grained B-γ-CsSnI3 thin films. Adv Energy Mater. 2016;6(24):1601130. http://dx.doi.org/10.1002/aenm.201601130. http://dx.doi.org/10.1002/aenm.201601130...
|
MASnI3
|
FTO/c-TiO2/PVSK/PTAA/Au |
1.30 |
0.23 |
3.32 |
40.70 |
0.31 |
One step method and SnF2
|
20168686 Ma L, Hao F, Stoumpos CC, Phelan BT, Wasielewski MR, Kanatzidis MG. Carrier diffusion lengths of over 500 nm in lead-free perovskite CH3NH3SnI3 Films. J Am Chem Soc. 2016;138(44):14750-5. http://dx.doi.org/10.1021/jacs.6b09257. PMid:27750426. http://dx.doi.org/10.1021/jacs.6b09257...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Au |
1.30 |
0.32 |
21.40 |
46.00 |
3.15 |
DMSO and SnF2-mediated crystallization and no Spiro-OMeTAD |
2015110110 Hao F, Stoumpos CC, Guo P, Zhou N, Marks TJ, Chang RP, et al. Solvent-mediated crystallization of CH3NH3SnI3 films for heterojunction depleted perovskite solar cells. J Am Chem Soc. 2015;137(35):11445-52. http://dx.doi.org/10.1021/jacs.5b06658. PMid:26313318. http://dx.doi.org/10.1021/jacs.5b06658...
|
FASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.41 |
0.24 |
24.45 |
36.00 |
2.10 |
Stable A cation choice,tin compensator (20%SnF2) and 500 nm TiO2
|
20154747 Koh TM, Krishnamoorthy T, Yantara N, Shi C, Leong WL, Boix PP, et al. Formamidinium tin-based perovskite with low Eg for photovoltaic applications. J Mater Chem A Mater Energy Sustain. 2015;3(29):14996-5000. http://dx.doi.org/10.1039/C5TA00190K. http://dx.doi.org/10.1039/C5TA00190K...
|
CsSnI2.9Br0.1
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
- |
0.22 |
24.16 |
33.00 |
1.76 |
Br doping and use of SnF2 additive |
2015187187 Sabba D, Mulmudi HK, Prabhakar RR, Krishnamoorthy T, Baikie T, Boix PP, et al. Impact of anionic Br- substitution on open circuit voltage in lead free perovskite (CsSnI3-xBrx). J Phys Chem C. 2015;119(4):1763-7. http://dx.doi.org/10.1021/jp5126624. http://dx.doi.org/10.1021/jp5126624...
|
MASnBr3
|
FTO/c-TiO2/PVSK/P3HT/Au |
2.20 |
0.50 |
4.27 |
49.10 |
1.12 |
Sequential evaporation, P3HT electron transport material and annealing at 150 oC. |
20158787 Jung M-C, Raga SR, Qi Y. Properties and solar cell applications of Pb-free perovskite films formed by vapor deposition. RSC Advances. 2016;6(4):2819-25. http://dx.doi.org/10.1039/C5RA21291J. http://dx.doi.org/10.1039/C5RA21291J...
|
MASn0.15Pb0.85X |
ITO/PEDOT:PSS/PVSK/PCBM/ C60-bis/Ag |
- |
0.76 |
19.10 |
66.00 |
10.10 |
Sn/Pb mixture |
2014170170 Zuo F, Williams ST, Liang P-W, Chueh C-C, Liao C-Y, Jen AK-Y. Binary-metal perovskites toward high-performance planar-heterojunction hybrid solar cells. Adv Mater. 2014;26(37):6454-60. http://dx.doi.org/10.1002/adma.201401641. PMid:25123496. http://dx.doi.org/10.1002/adma.201401641...
|
MASn0.5Pb0.5I3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.17 |
0.58 |
20.64 |
60.32 |
7.20 |
Mixed metal cations, bandgap engineering and HI/H3PO4 solvent |
20148383 Hao F, Stoumpos CC, Chang RPH, Kanatzidis MG. Anomalous band gap behavior in mixed sn and pb perovskites enables broadening of absorption spectrum in solar cells. J Am Chem Soc. 2014;136(22):8094-9. http://dx.doi.org/10.1021/ja5033259. PMid:24823301. http://dx.doi.org/10.1021/ja5033259...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.23 |
0.88 |
16.80 |
42.00 |
6.40 |
400 nm m-TiO2, device encapsulation and replacement of Li-TFSI with H-TFSI |
20141818 Noel NK, Stranks SD, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A-A, et al. Lead-free organic-inorganic tin halide perovskites for photovoltaic applications. Energy Environ Sci. 2014;7(9):3061-8. http://dx.doi.org/10.1039/C4EE01076K. http://dx.doi.org/10.1039/C4EE01076K...
|
MASnIBr2
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.75 |
0.82 |
12.30 |
57.00 |
5.73 |
Br doping |
20141919 Hao F, Stoumpos CC, Cao DH, Chang RPH, Kanatzidis MG. Lead-free solid-state organic-inorganic halide perovskite solar cells. Nat Photonics. 2014;8(6):489-94. http://dx.doi.org/10.1038/nphoton.2014.82. http://dx.doi.org/10.1038/nphoton.2014.8...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.30 |
0.72 |
15.18 |
50.07 |
5.44 |
2,6-lutidine andHI/H3PO4 solvent |
20148383 Hao F, Stoumpos CC, Chang RPH, Kanatzidis MG. Anomalous band gap behavior in mixed sn and pb perovskites enables broadening of absorption spectrum in solar cells. J Am Chem Soc. 2014;136(22):8094-9. http://dx.doi.org/10.1021/ja5033259. PMid:24823301. http://dx.doi.org/10.1021/ja5033259...
|
MASnI3
|
FTO/c-TiO2/m-TiO2/PVSK/Spiro/Au |
1.30 |
0.68 |
16.30 |
48.00 |
5.23 |
Solid state perovskite and 350 nm thick TiO2 film |
20141919 Hao F, Stoumpos CC, Cao DH, Chang RPH, Kanatzidis MG. Lead-free solid-state organic-inorganic halide perovskite solar cells. Nat Photonics. 2014;8(6):489-94. http://dx.doi.org/10.1038/nphoton.2014.82. http://dx.doi.org/10.1038/nphoton.2014.8...
|
MASn0.5Pb0.5I3
|
FTO/c-TiO2/m-TiO2/PVSK/P3HT/Au/Ag |
1.18 |
0.42 |
20.04 |
50.00 |
4.18 |
Hydrazine atmosphere, Pb/Sn ratio and P3HT |
2014151151 Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, et al. CH3NH3SnxPb1-xI3 perovskite solar cells covering up to 1060 nm. J Phys Chem Lett. 2014;5(6):1004-11. http://dx.doi.org/10.1021/jz5002117. PMid:26270980. http://dx.doi.org/10.1021/jz5002117...
|
CsSnI3
|
FTO/c-TiO2/m-TiO2/PVSK/m-MTDATA/Au |
1.30 |
0.24 |
22.70 |
37.00 |
2.02 |
SnF2 additive and 4, 4′, 4″-tris(N,N-phenyl-3-methylamino) triphenylamine |
2014154154 Kumar MH, Dharani S, Leong WL, Boix PP, Prabhakar RR, Baikie T, et al. Lead-free halide perovskite solar cells with high photocurrents realized through vacancy modulation. Adv Mater. 2014;26(41):7122-7. http://dx.doi.org/10.1002/adma.201401991. PMid:25212785. http://dx.doi.org/10.1002/adma.201401991...
|