Influence of Different Types of Treatments on Amazonian Vegetable Fibers on the Performance of Mortars Based on Portland Cement, Metakaolin and Fly Ash

Abstract

This study aimed to evaluate the physical, chemical, and mechanical properties of different Amazonian vegetable fibers to produce cementitious mortars reinforced with different types of vegetable fibers from the Amazon. Also, to analyze the influence of different types of chemical and physical treatments, on the direct tensile strength of vegetable fibers, water absorption of vegetable fibers and on the mechanical properties of compressive strength, flexural strength, and water absorption of mortars. Four vegetable fibers from the Amazon rainforest, from the Upper Rio Negro region (piassava, jute, tucum and razor grass) were used to produce cement composites with 50% Portland CPII-F cement and additions of supplementary cement materials (40% metakaolin and 10% fly ash), with cement mortar and sand trace 1:2:0.60. The cementitious composites were subjected to two types of curing: initial curing in air followed by final curing in water and curing in a pressurized autoclave with CO₂, both for 28 days. The treatments applied to the fibers were: washing with hot water; hornification; chemical treatment with sodium hydroxide and hybridization (hot water washing coupling, hornification, sodium hydroxide (NaOH) and application of hydrogen peroxide (H₂O₂)). As a result, the hybridization treatment increased the mechanical strength of the tucum fiber from 67.20 MPa (untreated fiber) to 318.80 MPa (treated), corroborating the increase in the crystallinity index from 59.84% to 66.73%. The flexural strength of cementitious composites reinforced with 4.5% tucum fibers and razor grass submitted to curing in an autoclave with CO₂ was, respectively, 49.61% and 61.75% higher than the reference composite (without fibers) in the water curing. Therefore, both the autoclave cure and the hybridization treatment proved to be viable for its application in composites with vegetable fibers.

Keywords:
Water Absorption; Natural Fibers; Cement Composites; Autoclaved cure; Mechanical properties