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Spectroscopic properties and electronic-optic parameters of complexes Ln(NO3)3.2DTPO.4H2O (Ln = Nd and Er)

Complexes with the composition Ln(NO3)3.2DTPO.4H2O (Ln = Nd and Er) were synthesized and characterized by infrared and visible absorption spectra (solid state and solution). The results of the absorption spectra in the solid state suggest that metal-ligand bonds are essentially electrostatic in all complexes. The absorption spectra of the nitrate salt solution presented smaller values of the oscillator strength when compared to the spectra of the complexes in the same solvent.

spectroscopic properties; neodymium; erbium


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