SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS

This review briefly describes the evolution of organometallic chemistry and photoredox catalysis as independent fields; followed by a more in-depth presentation and discussion of representative examples derived from their synergistic combination, which generally leads to powerful cross-coupling protocols. In this context, the rational deconvolution of these complex catalytic systems into their isolated, more simple components are evaluated in order to understand their properties and reactivities.

Keywords:
photoredox catalysis; photochemistry; metal catalysis; homogeneous catalysis; organic synthesis