Land application represents an efficient alternative for disposal of biosolids. However, depending on the origin (urban and/or domestic) and the treatment system, biosolids may contain high amounts of heavy metals, which can gradually build up in the soil. Soil chemical amendments in contaminated areas can reduce the bioavailability and mobility of heavy metals and, consequently, minimize the risks of their adverse effects on the environment. The objective of this study was to evaluate the effects of four chemical amendments [calcium carbonate (CaCO3), calcium sulfate (CaSO4), monobasic potassium phosphate (KH2PO4) and synthetic hydroxyapatite (HA)] on Zn, Cu, and Cd retention and distribution in Oxisols amended with biosolid. Due to the low solubility, HA was equilibrated at pH 4, 5, and 6. Surface soil samples (0-20 cm) of a Rhodic Acrudox (RA) and a Typic Haplorthox (HP) were used. Two grams of each soil sample were equilibrated in a dual- diffusion chamber with 2 g of heavily contaminated with heavy metals. The suspension was constantly stirred for a more uniform mixing of the solutions. When the equilibrium was reached (after approximately seven days), the solution was centrifuged, filtered and acidified. Copper, Zn, and Cd concentrations in solution were determined. The solid phases (soil and biosolid) were freeze-dried and sequential extractions of Zn, Cu and Cd were performed. The chemical amendments were efficient in Zn, Cd and, to a lesser extent, Cu immobilization. Calcium carbonate followed by HA (pH 6) was, in general, the most efficient treatment in reducing metal concentrations in solution. No heavy metal immobilization was obtained by HA equilibrated at pH 4 and 5. Chemical amendments markedly reduced the amounts of metals associated with the exchangeable fraction and increased the surface oxide/carbonate pool, especially in the treatments with CaCO3 and HA (pH 6).
tropical soils; hydroxyapatite; heavy metals; fractionation
