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Mechanical behavior and durability of mortars with quartzite and Portland cement after sulfate attack

Comportamento mecânico e durabilidade de argamassas com quartzito e cimento Portland após ataque com sulfato

ABSTRACT

The residues of ornamental rocks, especially quartzite, cause great environmental impact. More impulse has been given to research on the recycling of these residues over the last years, particularly for use as aggregates in concrete and mortar. Nevertheless, the studies conducted so far do not mention the behavior of the mortar blended with aggregates coming from residues of ornamental rocks when under chemical attacks in sulfate-rich environment. Thus, in the present study it was sought to add quartzite residues to the mortar, verifying its mechanical behavior and its durability when attacked by sodium sulfate (Na2SO4). The durability of the mortar blended with quartzite residues under sulfate attack was evaluated by the dimensional variation of the test specimens when immersed in sodium sulfate solution, according to the methodology of the NBR 13583 standard. Were used the following complementary techniques: simple compressive strength, X-ray diffraction and thermogravimetric and differential analysis. From the tests, it was verified that the mortars, after attack of sodium sulfate, presented dimensional expansions superior to 0.06%, as well as increased mechanical strength. Therefore, although it was found that the specimens incorporated with quartzite residues were attacked by sulfate, it was observed that it was not able to form sufficient secondary ettringite to mechanically damage the specimens submitted to the sodium sulfate attack.

Keywords
Alternative materials; quartzite residue; sulfates; durability

Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
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