Fe3O4 - Magnetite |
308, 542, 550, 560, 553, 650- 676, 690, 1322 |
[7[7] Xiao, K., Dong, C.-F., Li, X., et al., "Corrosion products and formation of mechanism during initial stage of atmospheric corrosion of carbon steel", Journal of Iron and Steel Research, International, 15, 5, 2008.],[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.],[14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.],[17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.], [20[20] Balasubramaniam, R., Ramesh Kumar A.V., Dillmann, P., "Characterization of rust on ancient Indian iron", Current Science, n. 85, v. 11, 2003.] |
γ-Fe2O3- Maghemite |
345, 510, 645, 660- 680, 710- 720, 1198, 1412, 1425, 1440 |
[7[7] Xiao, K., Dong, C.-F., Li, X., et al., "Corrosion products and formation of mechanism during initial stage of atmospheric corrosion of carbon steel", Journal of Iron and Steel Research, International, 15, 5, 2008.],[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.],[14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.],[17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.] |
α-Fe2O3- Haematite |
225-227, 245,292-295, 412-415, 500-501, 612-615, 1312, 1320 |
[7[7] Xiao, K., Dong, C.-F., Li, X., et al., "Corrosion products and formation of mechanism during initial stage of atmospheric corrosion of carbon steel", Journal of Iron and Steel Research, International, 15, 5, 2008.],[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.],[14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.],[17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.],[20[20] Balasubramaniam, R., Ramesh Kumar A.V., Dillmann, P., "Characterization of rust on ancient Indian iron", Current Science, n. 85, v. 11, 2003.] |
α-FeOOH- Goethite |
245-248, 293-303, 348, 386-397, 420, 480-485, 549-554, 675-686, 1002-1004, 1120, 1295 |
[7[7] Xiao, K., Dong, C.-F., Li, X., et al., "Corrosion products and formation of mechanism during initial stage of atmospheric corrosion of carbon steel", Journal of Iron and Steel Research, International, 15, 5, 2008.],[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.],[14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.],[17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.],[20[20] Balasubramaniam, R., Ramesh Kumar A.V., Dillmann, P., "Characterization of rust on ancient Indian iron", Current Science, n. 85, v. 11, 2003.] |
γ-FeOOH- Lepidocrocite |
248-255, 218, 374, 380, 528, 654-660, 695, 1054, 1300-1311
|
[7[7] Xiao, K., Dong, C.-F., Li, X., et al., "Corrosion products and formation of mechanism during initial stage of atmospheric corrosion of carbon steel", Journal of Iron and Steel Research, International, 15, 5, 2008.],[20[20] Balasubramaniam, R., Ramesh Kumar A.V., Dillmann, P., "Characterization of rust on ancient Indian iron", Current Science, n. 85, v. 11, 2003.],[21[21] Dunn, D.S., Bogart, M.B., Brossia, C.S., et al., "Corrosion of Iron Under Alternating Wet and Dry Conditions", Corrosion, 56, 5, 2000.],[22[22] Remazeilles, C., Refait, P., "On the formation of β-FeOOH (akaganeite) in chloride-containing environments", Corros Sci., v. 49, n.2, 2007. ] |
β-FeOOH- Akaganeite |
309-314, 330, 384, 380-388, 396, 400-415, 535-538, 722-745, 1389 |
[20[20] Balasubramaniam, R., Ramesh Kumar A.V., Dillmann, P., "Characterization of rust on ancient Indian iron", Current Science, n. 85, v. 11, 2003.],[21[21] Dunn, D.S., Bogart, M.B., Brossia, C.S., et al., "Corrosion of Iron Under Alternating Wet and Dry Conditions", Corrosion, 56, 5, 2000.],[22[22] Remazeilles, C., Refait, P., "On the formation of β-FeOOH (akaganeite) in chloride-containing environments", Corros Sci., v. 49, n.2, 2007. ],[23[23] Dunn, D.S., Bogart, M.B., Brossia, C.S., et al, "Corrosion of iron under alternating wet and dry conditions", Corrosion 99, San Antonio, Paper 223.], [24[24] Reguer, S., Neff, D., Remazeilles, C., et al., "Desalinisation of iron archaeological artefacts: understanding of chlorine removal mechanisms of the corrosion layers supported by characterisation techniques", In: Proc. of the Metal07 Conf., 17th - 21st Sept. Amsterdam, The Netherlands, pp 60-68, 2007.] |
δ-FeOOH- Feroxyhyte |
220, 295, 385, 400, 495, 655, 670-680, 1350
|
[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.], [14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.], [17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.] |
Fe(OH)2 -Ferrous hydroxide |
460, 550
|
[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.], [14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.], [17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.] |
Fe(OH)3
|
395, 696, 692, 1335 |
[13[13] Gui, J., Devine, T.M., Proc. Of the 12th Int. Corrosion Congress, Nace International, Houston, pp 2052-2063, 1993.], [14[14] Dunnwald, J., Otto, A., "An investigation of phase transitions in rust layers using Raman spectroscopy", Corros. Sci., v. 29, n. 9, 1989.], [15[15] Ohtsuka, T., Kubo, K., Sato, N., "Raman Spectroscopy of Thin Corrosion Films on Iron at 1000 to 15000 C in Air Corrosion", Corrosion, v.42, n.8, pp.476-481, 1986.], [16[16] Ohtsuka, T., "Raman Spectra of passive films of iron in neutral borate solution", Materials Transactions, v. 37, n. 1, 1996.], [17[17] Boucherit, N., Delicher, P., Joiret, S., et al., Materials Science Forum, v. 51, n.44, 1989.], [18[18] Thierry, D., Persson, D., Leygraf, C., et al., "In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals", J. Electrochem. Soc., v.135, n.2, 1988.], [19[19] Thibeau, R.J., Brown, C.W., Heidersbach, R.H., "Raman spectra of possible corrosion products of iron, Appl. Spectroscopy", Appl. Spectroscopy, v.32, n.6, 1978.] |
Green rust |
219, 269, 424, 433, 505, 511
|
[22[22] Remazeilles, C., Refait, P., "On the formation of β-FeOOH (akaganeite) in chloride-containing environments", Corros Sci., v. 49, n.2, 2007. ] |
SO42-
|
400-490, 965-1035
|
[12[12] Degen, I.A., Newman, G.A., "Raman spectra of inorganic ions", Spectrochimica Acta , v. 49A, n. 5/6, 1993.] |
SO32-
|
970-990
|
[12[12] Degen, I.A., Newman, G.A., "Raman spectra of inorganic ions", Spectrochimica Acta , v. 49A, n. 5/6, 1993.] |
ClO3-
|
480-490, 930-940
|
[12[12] Degen, I.A., Newman, G.A., "Raman spectra of inorganic ions", Spectrochimica Acta , v. 49A, n. 5/6, 1993.] |
ClO4-
|
450-475, 1145-1180, 935-955
|
[12[12] Degen, I.A., Newman, G.A., "Raman spectra of inorganic ions", Spectrochimica Acta , v. 49A, n. 5/6, 1993.] |