Acessibilidade / Reportar erro

Evaluation of corrosion inhibitors for reinforced concrete structures

ABSTRACT

Concrete reinforcement corrosion is one of the most important problems that diminish the durability of concrete structures, and it is often caused by the carbonation process and chloride ion attack in aggressive and marine environments. It is estimated that 90% of pathological problems affecting concrete structures worldwide lead to reinforcement corrosion. The research for materials with resistance to this deterioration process is fundamental to improve the durability and efficiency of concrete structures. In this context, the effect of three chemical additives, a commercial one based on nitrite salts, sodium molybdate (MoNa2O4) and sodium tungstate (Na2O4W.2H2O), used in contents of 1% and 2% in relation to the cement mass. Cylindrical, steel embedded, mortar samples (30 MPa strength class) were submitted to the potentiodynamic polarization test. The use of commercial additive was not efficient in reducing corrosion rates, but the effect of curing time reduced the mean corrosion rate from 4.7 mm/year at 60 days to 1.6 mm/year, at 90 days. The best results were obtained for the tungstate and molybdate additives, in which the addition of 1% of molybdate additive presented an efficiency rate of 50%, while 2% of tungstate additive presented an efficiency rate of 29%.

Keywords:
Corrosion; Steel reinforced concrete; Chemical additives

Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
E-mail: revmateria@gmail.com