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A review of FMLs performance test methods and index evaluation

ABSTRACT

With its excellent fatigue performance and high damage tolerance and other irreplaceable advantages, FMLs have gradually increased the demand in aerospace, rail transit, ship and other fields, and have put forward higher requirements for the speed and accuracy of its performance test and index evaluation. In this paper, the methods of performance test, analysis and index evaluation of FMLs are introduced from three aspects with carbon fiber and composite materials, mechanical properties and numerical simulation technology, details the common test methods, the latest technology and progress, and analyzes their advantages and disadvantages, so as to provide direction and reference for the performance test method and index evaluation of FMLs. Finally, the main development directions of the current performance testing methods and index evaluation of FMLs are briefly discussed.

Keywords
FMLs; Carbon Fiber Composites; Mechanical Properties; Numerical Simulation Technology; Outlook

1. INTRODUCTION

Fiber metal laminate (FMLs) is an intermixed composite material made of metal sheet and fiber reinforced composite alternately laying and curing at a certain temperature and pressure, also known as super-mixed laminate. FMLs integrates the characteristics of traditional fiber reinforced composites and metal materials, with high specific strength, specific stiffness, excellent fatigue performance and high damage tolerance, and has great development potential of in aerospace, rail transit, shipping and other fields [1[1] AD, V.J., WILLEM, G., Fibre metal laminates: an introduction, 1 st., Berlin, Springer Science & Business Media, 2011.,2[2] DING, Z., WANG, H., LUO, J., et al., “A review on forming technologies of fibre metal laminates”, International Journal of Lightweight Materials and Manufacture, v. 4, n. 1, pp. 110–126, Mar. 2021. doi: http://dx.doi.org/10.1016/j.ijlmm.2020.06.006.
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].

With the increasing requirements of large aircraft for lightweight, integration and damage tolerance capacity, carbon fiber reinforced composite material is widely used in FMLs for its irreplaceable advantages of high specific modulus, high specific strength, fatigue resistance, higher residual strength and higher impact strength [4[4] VERMEEREN, C., “An historic overview of the development of fibre metal laminates”, Applied Composite Materials, v. 10, n. 4, pp. 189–205, July 2003. doi: http://dx.doi.org/10.1023/A:1025533701806.
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https://doi.org/10.1016/j.ijadhadh.2016....
]. The third generation of FMLs with epoxy resin-based carbon fiber reinforced aluminum alloy material, namely CARALL. However, research shows, there is a high potential difference between carbon fiber and aluminum alloy. The composite electrocouple corrosion of the two intensifies the lamina corrosion, and it is difficult to use in an environment of more than 120 °C, which has become the main obstacle that CARALL is still difficult to commercialize [7[7] XIA, Y., WANG, Y., ZHOU, Y., et al., “Effect of strain rate on tensile behavior of carbon fiber reinforced aluminum laminates”, Materials Letters, v. 61, n. 1, pp. 213–215, Jan. 2007. doi: http://dx.doi.org/10.1016/j.matlet.2006.04.043.
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]. In order to overcome the above problems, TiGr, namely the fourth generation of FMLs, came into being, which uses graphite fiber reinforced polyether ether ketone composite material combined with titanium alloy to form. TiGr does not have corrosion problems, but its low research maturity, high manufacturing cost, and poor fracture toughness limit its application [9[9] HU, Y.B., LI, H.G., CAI, L., et al., “Preparation and properties of Fibre-Metal Laminates based on carbon fibre reinforced PMR polyimide”, Composites. Part B, Engineering, v. 69, pp. 587–591, Feb. 2015. doi: http://dx.doi.org/10.1016/j.compositesb.2014.11.011.
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In addition to the development of new material system, the researchers continue to enrich and improve the failure mechanism and damage mechanism through theoretical analysis and experimental research. In addition, as an important structural materials of aerospace, rail transit, FMLs need before the application of the system performance analysis and index evaluation, need great manpower, time, and material cost. In the background, to carry out fast and stable and reliable FMLs material performance test and index evaluation, called the focus of many scholars. Among them, the observation of appearance and microstructure, the detection of physical and chemical properties, the detection of mechanical properties, and other items that especially need to be tested, are all the focus of current research.

Commonly used standards in China including national standards (GB), aviation standards (HB) and the American materials association standard (ASTM D), etc., respectively for FMLs performance test and index evaluation method has carried on the detailed regulation, scholars on the basis of related experiments, and constantly optimize and improve the experimental equipment, method, in order to obtain more consistent with the engineering application effect [12[12] HE, W., WANG, L., LIU, H., et al., “On impact behavior of fiber metal laminate (FML) structures: a state-of-the-art review”, Thin-Walled Structures, v. 167, pp. 1–33, Oct. 2021.,13[13] YOU, M., LI, M.B., YUAN, Y.L., et al., “Review of experimental techniques for impact property of adhesive bonds”, International Journal of Adhesion and Adhesives, v. 100, pp. 1–15, July 2020. doi: http://dx.doi.org/10.1016/j.ijadhadh.2020.102620.
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https://doi.org/10.1016/j.ijimpeng.2021....
]. Based on ASTM D standard, this paper introduces the method of common performance test and index evaluation of FMLs, focuses on the latest technology, method and progress, and analyzes its advantages and disadvantages, and briefly discusses the main development direction of current FMLs performance test method and index evaluation, FMLs performance test method and index evaluation provide reference and research direction.

2. TESTING AND INDEX EVALUATION OF CARBON FIBER AND COMPOSITE MATERIALS

The properties of carbon fiber and composites have an important influence on the mechanical properties of FMLs. For example, the surface of carbon fiber affects the excellent performance of the composite material. The infiltration of the resin to the fiber surface is the condition that the fiber and the resin form a close interface and combine, and the binding strength of the interface affects the overall performance of the composite materials [16[16] ZHOU, Y., FAN, M., CHEN, L., “Interface and bonding mechanisms of plant fibre composites: an overview”, Composites. Part B, Engineering, v. 101, pp. 31–45, Sept. 2016. doi: http://dx.doi.org/10.1016/j.compositesb.2016.06.055.
https://doi.org/10.1016/j.compositesb.20...
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].

2.1. Surface characteristic test of carbon fiber

The surface properties of carbon fiber include fiber surface roughness, fiber surface chemical properties, specific area of fiber surface, etc. The surface properties of carbon fiber directly affect the surface properties of composites, and thus affect their mechanical macroscopic properties [19[19] MOHAMMADI, R., NAJAFABADI, M.A., SAGHAFI, H., et al., “The effect of mode II fatigue crack growth rate on the fractographic features of CFRP composite laminates: an acoustic emission and scanning electron microscopy analysis”, Engineering Fracture Mechanics, v. 241, pp. 1–14, Jan. 2021. doi: http://dx.doi.org/10.1016/j.engfracmech.2020.107408.
https://doi.org/10.1016/j.engfracmech.20...
, 20[20] MAZARBHUIYA, R.M., DUTTA, H., DEBNATH, K., et al., “Surface modification of CFRP composite using reverse-EDM method”, Surfaces and Interfaces, v. 18, pp. 1–7, Mar. 2020. doi: http://dx.doi.org/10.1016/j.surfin.2020.100457.
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]. In general, the rougher the carbon fiber surface, the larger the specific surface area, the better the bonding of the interface; the more polar functional groups on the carbon fiber surface, the more favorable the adhesion of carbon fiber and resin; and the macroscopic mechanical properties of carbon fiber composites.

The common testing and evaluation methods of fiber surface characteristics mainly include SEM (Scanning Electron Microscope), TEM (Transmission Electron Microscope), EDX (Energy Dispersive X-Ray Spectroscopy), AES (Auger Electron Spectrometry), XRD (X-ray diffraction), AFM (Atomic Force Microscope), LRS (Laser Raman Spectrometer), XPS (X-ray photoelectron spectroscopy), BET (Specific surface area test), FTIR (Fourier Transform Infrared Spectrometer), etc. The main applications are shown in the Table 1.

Table 1.
Presents the test and evaluation methods of the common fiber surface properties [21[21] KWON, D.J., KIM, J.H., DEVRIES, K.L., et al., “Optimized epoxy foam interface of CFRP/Epoxy Foam/CFRP sandwich composites for improving compressive and impact properties”, Journal of Materials Research and Technology, v. 11, pp. 62–71, Mar. 2021. doi: http://dx.doi.org/10.1016/j.jmrt.2021.01.015.
https://doi.org/10.1016/j.jmrt.2021.01.0...
, 22[22] Sumit Dash, S., Gangineni, P. K., Gupta K.B.G., et al., “Evaluation of mechanical behaviour of graphene oxide grafted CFRP composites: a comparison of anodic and cathodic EPD”, Advances in Materials and Processing Technologies, v. 8, n. 3, pp. 1395–1403, June 2021.].

SEM is often used for the observation of interface morphology, AFM can observe the interface morphology more intuitively and accurately, and quantitatively analyze the surface roughness of fiber; XPS and FTIR can analyze the chemical composition of carbon fiber surface; XPS can obtain the electronic structure, element composition and chemical state of the material surface, and has higher sensitivity [23[23] SHARMA, M., GAO, S., MÄDER, E., et al., “Carbon fiber surfaces and composite interphases”, Composites Science and Technology, v. 102, n. 6, pp. 35–50, Oct. 2014. doi: http://dx.doi.org/10.1016/j.compscitech.2014.07.005.
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,24[24] ZHOU, Y.N., LI, W., “The performance evaluation of carbon fiber and composite”, Hi-Tech Fiber & Application, v. 39, n. 6, pp. 11–16, Dec. 2014.,25[25] LI, Y., XU, N., LYU, H., et al., “Enhanced mechanical and tribological properties of carbon fiber/PEEK composites by hydroxylated boron nitride nanosheets and polyetherimide sizing agents”, Composites Science and Technology, v. 232, n. 8, pp. 1–8, Feb. 2023. doi: http://dx.doi.org/10.1016/j.compscitech.2022.109851.
https://doi.org/10.1016/j.compscitech.20...
].

2.2. Resin infiltration performance test and index evaluation

The infiltration of carbon fiber and resin indicates the difficulty of the resin immersed into the fiber bundle. If the infiltration is poor, the composite material will eventually contain pores and defects in the composite material, and affect the final macroscopic mechanical properties of the composite material [26[26] SUN, Y., FAN, W., SONG, C., et al., “Effects of stitch yarns on interlaminar shear behavior of three-dimensional stitched carbon fiber epoxy composites at room temperature and high temperature”, Advanced Composites and Hybrid Materials, v. 5, n. 3, pp. 1951–1965, July 2022. doi: http://dx.doi.org/10.1007/s42114-022-00526-y.
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,27[27] XU, Z., YANG, T., NAKAMURA, M., et al., “Effect of carbon powder surface treatment on carbon fiber reinforced PA composites”, Energy Procedia, v. 89, pp. 15–23, June 2016. doi: http://dx.doi.org/10.1016/j.egypro.2016.05.003.
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,28[28] SUJON, M.A.S., HABIB, M.A., ABEDIN, M.Z., “Experimental investigation of the mechanical and water absorption properties on fiber stacking sequence and orientation of jute/carbon epoxy hybrid composites”, Journal of Materials Research and Technology, v. 9, n. 5, pp. 10970–10981, Sept. 2020. doi: http://dx.doi.org/10.1016/j.jmrt.2020.07.079.
https://doi.org/10.1016/j.jmrt.2020.07.0...
]. Common tests and index evaluation of the infiltration properties of composite materials include contact angle, surface energy and adhesion work.

2.2.1. Contact angle

The contact angle is an important indicator to describe the ability of liquid to solid wetting. The better the carbon fiber bundle infiltration, the easier the resin is to soak in carbon fiber, the more conducive to the preparation of composite materials [29[29] ZHANG, C., LING, Y., ZHANG, X., et al., “Ultra-thin carbon fiber reinforced carbon nanotubes modified epoxy composites with superior mechanical and electrical properties for the aerospace field”, Composites. Part A, Applied Science and Manufacturing, v. 163, pp. 1–9, Dec. 2022. doi: http://dx.doi.org/10.1016/j.compositesa.2022.107197.
https://doi.org/10.1016/j.compositesa.20...
]. Measurement of the contact angle is difficult due to the fine and soft fibers. The methods used for fiber contact angle measurement are seat drop method, Wilhelmy and Washburn.

Base drop method, also known as droplet method, is the most commonly used contact angle testing method. The seat drop method is completed by using optical contact angle meter, from manual instrument to fully automatic system. In the seat drop method, the image of the droplet is taken by the high-resolution camera, and the air-liquid interface tangent is made through the junction of gas, solid and liquid, and then the angle is automatically measured by the software. Base method is a fast non-destructive method to characterize the chemistry of material surface, and it is also often used to calculate surface free energy [30[30] SCHANZ, J., MEINHARD, D., DOSTAL, I., et al., “Comprehensive study on the influence of different pretreatment methods and structural adhesives on the shear strength of hybrid CFRP/aluminum joints”, The Journal of Adhesion, v. 98, n. 12, pp. 1–29, June 2021., 31[31] MITCHELL, B., SADEK, A., KINSEY, B., “Advantages of water droplet machining over abrasive waterjet cutting of carbon fiber reinforced polymer”, Manufacturing Letters, v. 33, pp. 342–348, Sep. 2022. doi: http://dx.doi.org/10.1016/j.mfglet.2022.07.041.
https://doi.org/10.1016/j.mfglet.2022.07...
].

In Wilhelmy test, when a part of the solid is inserted into the liquid, the liquid will rise or fall along the vertical wall of the solid, and the contact angle is determined by measuring the tensile force (thrust) of the liquid on the solid, i.e., the wetting force. Wilhelmy Simple equipment, through the precision motor to accurately control the movement speed of the lifting table, precision balance can record the changes in the solid surface in the hand, the balance after zero measurement does not have to consider the influence of gravity, easy operation, do not need to do any correction [32[32] BADAKHSH, A., AN, K.H., KIM, B.J., “Enhanced surface energetics of CNT-grafted carbon fibers for superior electrical and mechanical properties in CFRPs”, Polymers, v. 12, n. 6, pp. 1–15, June 2020. doi: http://dx.doi.org/10.3390/polym12061432. PubMed PMID: 32604903.
https://doi.org/10.3390/polym12061432...
].

The Washburn method is mainly based on the capillary siphon effect of the liquid in the porous material. During the test, the carbon fiber was loaded into the glass tube closed with the microporous diaphragm at the lower end, and dropped to the liquid level in parallel. The change curve of the infiltration weight gain to the infiltration time was measured, and the contact angle was obtained through the own software of the instrument. The contact angle using the balance method to measure the fiber-resin system has high requirements on the test conditions and cumbersome operation. It is necessary to ensure that the two measurement states are completely consistent [33[33] WANG, J., FUENTES, C.A., ZHANG, D., et al., “Wettability of carbon fibres at micro-and mesoscales”, Carbon, v. 120, pp. 438–446, Aug. 2017. doi: http://dx.doi.org/10.1016/j.carbon.2017.05.055.
https://doi.org/10.1016/j.carbon.2017.05...
, 34[34] HONG, M.K., CHOI, W.K., PARK, J.H., et al., “Relationship between functionalized multi-walled carbon nanotubes and damping properties of multi-walled carbon nanotubes/carbon fiber-reinforced plastic composites for shaft”, Journal of Nanoscience and Nanotechnology, v. 20, n. 11, pp. 6862–6870, Nov. 2020. doi: http://dx.doi.org/10.1166/jnn.2020.18810. PubMed PMID: 32604528.
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].

2.2.2. Surface energy

The surface free energy of carbon fiber is an important physical quantity to describe and determine the surface properties of the fiber. At present, the commonly used methods to test the surface energy mainly include contact angle method and reverse gas chromatography (IGC method). The advantages and disadvantages of the two are shown in the Table 2.

Table 2.
The comparation of contact angle method with IGC method [35[35] LINDSAY, B., ABEL, M.L., WATTS, J.F., “A study of electrochemically treated PAN based carbon fibres by IGC and XPS”, Carbon, v. 45, n. 12, pp. 2433–2444, Oct. 2007. doi: http://dx.doi.org/10.1016/j.carbon.2007.04.017.
https://doi.org/10.1016/j.carbon.2007.04...
,36[36] HARDER, S., SCHMUTZLER, H., HERGOSS, P., et al., “Effect of infrared laser surface treatment on the morphology and adhesive properties of scarfed CFRP surfaces”, Composites. Part A, Applied Science and Manufacturing, v. 121, pp. 299–307, June 2019. doi: http://dx.doi.org/10.1016/j.compositesa.2019.02.025.
https://doi.org/10.1016/j.compositesa.20...
,37[37] JESSON, D.A., WATTS, J.F., “The interface and interphase in polymer matrix composites: effect on mechanical properties and methods for identification”, Polymer Reviews (Philadelphia, Pa.), v. 52, n. 3, pp. 321–354, Sept. 2012. doi: http://dx.doi.org/10.1080/15583724.2012.710288.
https://doi.org/10.1080/15583724.2012.71...
].

The IGC method takes the carbon fiber as the probe molecule, and the known small molecule liquid is used as the probe molecule. Under certain conditions, the gasified probe molecule is used to bring the gasification probe molecule into the chromatographic column. The surface energy of the stationary phase is studied by testing the retention time of the probe molecule through the chromatographic column. The contents of IGC detection mainly include: dispersion and polar surface energy, BET, specific surface area, adsorption heat, surface acid/alkaline analysis, etc. [38[38] VICKERS, P.E., WATTS, J.F., PERRUCHOT, C., et al., “The surface chemistry and acid-base properties of a PAN-based carbon fibre”, Carbon, v. 38, n. 5, pp. 675–689, Mar. 2000. doi: http://dx.doi.org/10.1016/S0008-6223(99)00137-2.
https://doi.org/10.1016/S0008-6223(99)00...
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].

2.2.3. The adhesive work

After the infiltration of resin and carbon fiber, the surface disappears and then the interface between resin and carbon fiber is produced. When the resin surface per unit area and the surface of carbon fiber adhere, the maximum attack is called adhesion work. The greater the greater the adhesion work, the better the infiltration, the more conducive to the formation of composite materials [43[43] SHA, J., LÜ, Z., SHA, R., et al., “Improved wettability and mechanical properties of metal coated carbon fiber-reinforced aluminum matrix composites by squeeze melt infiltration technique”, Transactions of Nonferrous Metals Society of China, v. 31, n. 2, pp. 317–330, Feb. 2021. doi: http://dx.doi.org/10.1016/S1003-6326(21)65498-5.
https://doi.org/10.1016/S1003-6326(21)65...
]. The adhesion work is the calculated value, the Young-Dupre method calculates the adhesion work by measuring the contact angle, and the Wu method measures the relevant surface energy, dispersion component and polar component to calculate the adhesion work by the IGC method [44[44] ALTAY, B.N., FLEMING, P.D., RAHMAN, M.A., et al., “Controlling unequal surface energy results caused by test liquids: the case of UV/O3 Treated PET”, Scientific Reports, v. 12, n. 1, pp. 6772, Apr. 2022. doi: http://dx.doi.org/10.1038/s41598-022-10816-6. PubMed PMID: 35474087.
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,45[45] DRELICH, J.W., BOINOVICH, L., CHIBOWSKI, E., et al., “Contact angles: History of over 200 years of open questions”, Surface Innovations, v. 8, n. 1–2, pp. 3–27, Feb. 2019. doi: http://dx.doi.org/10.1680/jsuin.19.00007.
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,46[46] CAUICH-CUPUL, J.I., HERRERA-FRANCO, P.J., GARCÍA-HERNÁNDEZ, E., et al., “Factorial design approach to assess the effect of fiber-matrix adhesion on the IFSS and work of adhesion of carbon fiber/polysulfone-modified epoxy composites”, Carbon Letters, v. 29, n. 4, pp. 345–358, May 2019. doi: http://dx.doi.org/10.1007/s42823-019-00039-7.
https://doi.org/10.1007/s42823-019-00039...
]. It is shown that the results measured by the Wu method are higher than that measured by the IGC method, because the contact angle test reflects the average effect on the fiber surface, while the probe molecules are easier to interact with the high energy points on the fiber surface [47[47] OKHRIMENKO, D.V., BUDI, A., CECCATO, M., et al., “Wettability and hydrolytic stability of 3-aminopropylsilane coupling agent and phenol-urea-formaldehyde binder on silicate surfaces and fibers”, Polymer Degradation & Stability, v. 183, pp. 1–13, Jan. 2021. doi: http://dx.doi.org/10.1016/j.polymdegradstab.2020.109431.
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].

2.3. Interfacial binding strength test of carbon fiber composites

Interface is an important combination part of carbon fiber composite materials, which has an important influence on the mechanical properties of carbon fiber composites [49[49] HADDEN, C.M., KLIMEK-MCDONALD, D.R., PINEDA, E.J., et al., “Mechanical properties of graphene nanoplatelet/carbon fiber/epoxy hybrid composites: Multiscale modeling and experiments”, Carbon, v. 95, pp. 100–112, Dec. 2015. doi: http://dx.doi.org/10.1016/j.carbon.2015.08.026.
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https://doi.org/10.1177/0954008320957398...
]. It is of great significance to accurately measure and express the binding strength of the interface. Methods for characterizing interface binding strength are mainly in macroscopic and microscopic ways.

2.3.1. Macroscopic test and evaluation of the interface binding strength

The macroscopic testing methods of interface binding strength of carbon fiber composites mainly include tensile method, three-point bending method, shear method, Nuo ear ring (NOL), etc. [52[52] ZADORECKI, P., FLODIN, P., “Surface modification of cellulose fibers. II. The effect of cellulose fiber treatment on the performance of cellulose-polyester composites”, Journal of Applied Polymer Science, v. 30, n. 10, pp. 3971–3983, Oct. 1985. doi: http://dx.doi.org/10.1002/app.1985.070301003.
https://doi.org/10.1002/app.1985.0703010...
,53[53] YAN, M., LIU, L., CHEN, L., et al., “Radiation resistance of carbon fiber-reinforced epoxy composites optimized synergistically by carbon nanotubes in interface area/matrix”, Composites. Part B, Engineering, v. 172, pp. 447–457, Sept. 2019. doi: http://dx.doi.org/10.1016/j.compositesb.2019.04.041.
https://doi.org/10.1016/j.compositesb.20...
,54[54] KIMURA, M., WATANABE, T., TAKEICHI, Y., et al., “Nanoscopic origin of cracks in carbon fibre-reinforced plastic composites”, Scientific Reports, v. 9, n. 1, pp. 19300, Dec. 2019. doi: http://dx.doi.org/10.1038/s41598-019-55904-2. PubMed PMID: 31848424.
https://doi.org/10.1038/s41598-019-55904...
]. Carbon fiber composite interface combined strength test method and the FMLs mechanical properties test method is almost the same, will be detailed in the FMLs mechanical properties test and evaluation index, it is worth noting that in the tensile performance test, although the lateral tensile to the interface bonding strength is very sensitive, it is difficult to get stable data, but is still the only effective method to characterize the interface tensile properties of composite materials [55[55] ZHANG, X., XU, Y., WANG, M., et al., “A powder-metallurgy-based strategy toward three-dimensional graphene-like network for reinforcing copper matrix composites”, Nature Communications, v. 11, n. 1, pp. 2775, June 2020. doi: http://dx.doi.org/10.1038/s41467-020-16490-4. PubMed PMID: 32488100.
https://doi.org/10.1038/s41467-020-16490...
, 56[56] SADASIVUNI, K.K., SAHA, P., ADHIKARI, J., et al., “Recent advances in mechanical properties of biopolymer composites: a review”, Polymer Composites, v. 41, n. 1, pp. 32–59, Aug. 2020. http://dx.doi.org/10.1002/pc.25356.
https://doi.org/10.1002/pc.25356...
]. The ring test method can not only evaluate the bonding performance of the interface, but also evaluate the tensile strength, which is currently widely used [57[57] CHARAN, V.S.S., VARDHAN, A.V., RAJ, S., et al., “Experimental characterization of CFRP by NOL ring test”, Materials Today: Proceedings, v. 18, pp. 2868–2874, Nov. 2019. doi: http://dx.doi.org/10.1016/j.matpr.2019.07.154.
https://doi.org/10.1016/j.matpr.2019.07....
, 58[58] XU, L.Y., LU, J.R., LI, K.M., et al., “Experimental study of CFRP laser surface modification and bonding characteristics of CFRP/Al6061 heterogeneous joints”, Composite Structures, v. 283, pp. 1–6, Nov. 2022. doi: http://dx.doi.org/10.1016/j.compstruct.2021.115030.
https://doi.org/10.1016/j.compstruct.202...
].

2.3.2. Microscopic test and evaluation of the interface binding strength

The microscopic test of the interface binding strength of carbon fiber composites generally adopts the single fiber method, including the single fiber fracture method, the single fiber extraction method, and the single filament embedding method, etc.

The single fiber fracture method places a single fiber in the resin matrix for curing, and the sample is stretched along the fiber direction. Under the condition that the matrix is broken, the single fiber breaks and reaches the saturation state, and then the interface binding strength is calculated through the formula.

The single fiber extraction method requires that the single fiber should be wrapped straight in the resin matrix. The test principle is shown in the figure. By recording the force of the fiber deadhesion moment, the debonding force of the fiber is calculated by the formula. During the experiment, it should be noted that the interface binding strength increases linearly as the fiber embedding length increases [59[59] NAIK, D.L., SHARMA, A., CHADA, R.R., et al., “Modified pullout test for indirect characterization of natural fiber and cementitious matrix interface properties”, Construction and Building Materials, v. 208, pp. 381–393, May 2019. doi: http://dx.doi.org/10.1016/j.conbuildmat.2019.03.021.
https://doi.org/10.1016/j.conbuildmat.20...
].

Single fiber pressing method presses the fiber out of the fiber from the resin at the end of the fiber with very sharp diamond. This method requires that the fiber is perpendicular to the interface with the composite material, and the test method is relatively complex, and the data collation and analysis is mainly realized through finite element analysis [60[60] NGUYEN, H., KAAS, A., KINNUNEN, P., et al., “Fiber reinforced alkali-activated stone wool composites fabricated by hot-pressing technique”, Materials & Design, v. 186, pp. 1–14, Jan. 2020. doi: http://dx.doi.org/10.1016/j.matdes.2019.108315.
https://doi.org/10.1016/j.matdes.2019.10...
].

3. MECHANICAL PROPERTIES TEST AND INDEX EVALUATION

Mechanical testing of the structure of FMLs is a prerequisite for their design, structure optimization, etc. [61[61] ALDERLIESTEN, R.C., BENEDICTUS, R., “Fiber/metal composite technology for future primary aircraft structures”, Journal of Aircraft, v. 45, n. 4, pp. 1182–1189, May 2008. doi: http://dx.doi.org/10.2514/1.33946.
https://doi.org/10.2514/1.33946...
]. For common mechanical properties, mainly include interlayer shear failure, bending failure, fatigue failure, etc., for specific working conditions, including high and low speed impact, high temperature resistance, salt spray and other performance tests, this paper only considers the most basic mechanical properties.

3.1. Layer plate shear failure and index evaluation

In the process of assembly and service, if FMLs are subjected to lateral load or torsion force, it is easy to produce local interlayer debonding, and then layer expansion, leading to the overall failure of the structure [62[62] KHAZAEI POUL, M., NATEGHI-ALAHI, F., ZHAO, X.L., “Experimental testing on CFRP strengthened thin steel plates under shear loading”, Thin-walled Structures, v. 109, pp. 217–226, Dec. 2016. doi: http://dx.doi.org/10.1016/j.tws.2016.09.026.
https://doi.org/10.1016/j.tws.2016.09.02...
,63[63] JAMES, S., DANG, C., “Investigation of shear failure load in ultrasonic additive manufacturing of 3D CFRP/Ti structures”, Journal of Manufacturing Processes, v. 56, pp. 1317–1321, Aug. 2020. doi: http://dx.doi.org/10.1016/j.jmapro.2020.04.026.
https://doi.org/10.1016/j.jmapro.2020.04...
,64[64] LIU, Q., GUO, B., CHEN, P., et al., “Investigating ballistic resistance of CFRP/polyurea composite plates subjected to ballistic impact”, Thin-walled Structures, v. 166, pp. 1–13, Sept. 2021. doi: http://dx.doi.org/10.1016/j.tws.2021.108111.
https://doi.org/10.1016/j.tws.2021.10811...
]. Therefore, appropriate methods are needed to characterize the interlayer shear resistance of FMLs.

The interlayer shear strength (ILSS) is the interlayer shear stress when the sample fails or the load reaches the maximum value, which characterizes the interlayer shear strength of the materials [65[65] JAKUBCZAK, P., BIENIAS, J., SUROWSKA, B., “Interlaminar shear strength of fibre metal laminates after thermal cycles”, Composite Structures, v. 206, pp. 876–887, Dec. 2018. doi: http://dx.doi.org/10.1016/j.compstruct.2018.09.001.
https://doi.org/10.1016/j.compstruct.201...
]. At present, the test methods for evaluating the interlayer shear performance of composite materials mainly include compression experiment, short beam method, double groove tensile shear method, V-groove shear method, etc. Researchers at home and abroad aim for the shear strength test of fiber metal laminate, mainly by short beam method, and the main test standards and parameters are shown in the Table 3.

Table 3.
Test standards and parameters of short beam method [66[66] WANG, Y., KOU, K., ZHUO, L., et al., “Preparation of boz/glass fibers/cyanate ester resins laminated composites”, Polymer Composites, v. 38, n. 3, pp. 523–527, May 2017. doi: http://dx.doi.org/10.1002/pc.23611.
https://doi.org/10.1002/pc.23611...
,67[67] HU, J., HU, Y., DENG, S.F., et al., “Synthesis and properties of a novel silicon-containing phthalonitrile resin and its quartz-fiber-reinforced composites”, High Performance Polymers, v. 32, n. 10, pp. 1112–1121, June 2020. doi: http://dx.doi.org/10.1177/0954008320924090.
https://doi.org/10.1177/0954008320924090...
,68[68] TSERPES, K., TZATZADAKIS, V., KATSIROPOULOS, C., “Effect of hygrothermal ageing on the interlaminar shear strength of carbon fiber-reinforced rosin-based epoxy bio-composites”, Composite Structures, v. 226, pp. 1–3, Oct. 2019. doi: http://dx.doi.org/10.1016/j.compstruct.2019.111211.
https://doi.org/10.1016/j.compstruct.201...
,69[69] TAO, J., LI, H.G., HU, Y.B., Mechanical properties and forming technology of fiber metal lamination, 1 st., Beijing, Science Press, 2017.,70[70] CHEN, Y., WANG, Y., WANG, H., “Research progress on interlaminar failure behavior of fiber metal laminates”, Advances in Polymer Technology, v. 2020, n. 1, pp. 1–20, Mar. 2020. doi: http://dx.doi.org/10.1002/(SICI)1098-2329(199921)18:1<1::AID-ADV1>3.0.CO,2-0.
https://doi.org/10.1002/(SICI)1098-2329(...
].

It is worth noting that, compared with the short beam method, the double beam method has a pure shear stress point, which alleviates the influence of bending stress on the shear strength between layers to a certain extent [71[71] HAPKE, J., GEHRIG, F., HUBER, N., et al., “Compressive failure of UD-CFRP containing void defects: In situ SEM microanalysis”, Composites Science and Technology, v. 71, n. 9, pp. 1242–1249, June 2011. doi: http://dx.doi.org/10.1016/j.compscitech.2011.04.009.
https://doi.org/10.1016/j.compscitech.20...
, 72[72] LI, L.J., GUO, Y.C., LIU, F., et al., “An experimental and numerical study of the effect of thickness and length of CFRP on performance of repaired reinforced concrete beams”, Construction & Building Materials, v. 20, n. 10, pp. 901–909, Dec. 2006. doi: http://dx.doi.org/10.1016/j.conbuildmat.2005.06.020.
https://doi.org/10.1016/j.conbuildmat.20...
]. At the same time, considering the application of double-beam shear method to resin-based composites, it has some specificity compared with the traditional interlayer shear performance test, and is gradually widely used in the shear performance test of FMLs [73[73] TAO, N., CHEN, G., YU, T., et al., “Dual-beam laser drilling process for thick carbon fiber reinforced plastic composites plates”, Journal of Materials Processing Technology, v. 281, pp. 1–12, July 2020. doi: http://dx.doi.org/10.1016/j.jmatprotec.2020.116590.
https://doi.org/10.1016/j.jmatprotec.202...
,74[74] PAWLAK, A.M., GÓRNY, T., DOPIERAŁA, Ł., et al., “The use of CFRP for structural reinforcement-literature review”, Metals, v. 12, n. 9, pp. 1–24, Sept. 2022. doi: http://dx.doi.org/10.3390/met12091470.
https://doi.org/10.3390/met12091470...
,75[75] LI, A., WANG, H., LI, H., et al., “Estimation of bond strength and effective bond length for the double strap joint between carbon fiber reinforced polymer (CFRP) plate and corroded steel plate”, Polymers, v. 14, n. 15, pp. 1–16, July 2022. doi: http://dx.doi.org/10.3390/polym14153069. PubMed PMID: 35956583.
https://doi.org/10.3390/polym14153069...
].

3.2. Bending failure and index evaluation

In the process of service, if FMLs are subjected to a large bending moment, they will produce bending deformation. The most commonly used method to evaluate the bending performance is the three-point bending experiment. At present, there is no relevant standard for FLs bending performance test at home and abroad. Most of the bending performance evaluation directly uses the traditional experimental method of the polymer matrix composite material, and the commonly used standards are ISO 14125-1998, ASTM D 790 and GB 1449-2005. The specific experimental method is described in 3.1 and will not be described.

3.3. Fatigue performance test and index evaluation

During the service of FMLs, the repeated action of fatigue loads will lead to the damage and failure of structural materials. Compared with traditional metal materials, the biggest characteristic of FMLs is its better damage fatigue and damage tolerance performance [76[76] ALDERIESTEN, R., “Fatigue in fibre metal laminates: The interplay between fatigue in metals and fatigue in composites”, Fatigue & Fracture of Engineering Materials & Structures, v. 42, n. 11, pp. 2414–2421, Feb. 2019. doi: http://dx.doi.org/10.1111/ffe.12995.
https://doi.org/10.1111/ffe.12995...
]. FML fatigue injury includes the expansion of metal layer, matrix cracking, interface debonding, interlayer delamination and fiber fracture, and the crack expansion of metal layer and fiber layer layer coupling and influence each other [77[77] GIALLANZA, A., PARRINELLO, F., RUGGIERO, V., et al., “Fatigue crack growth of new FML composites for light ship buildings under predominant mode II loading condition”, International Journal on Interactive Design and Manufacturing, v. 14, n. 1, pp. 77–87, Nov. 2020. doi: http://dx.doi.org/10.1007/s12008-019-00617-z.
https://doi.org/10.1007/s12008-019-00617...
,78[78] PRASAD, E.V., SIVATEJA, C., SAHU, S.K., “Effect of nanoalumina on fatigue characteristics of fiber metal laminates”, Polymer Testing, v. 85, pp. 1–13, May 2020. doi: http://dx.doi.org/10.1016/j.polymertesting.2020.106441.
https://doi.org/10.1016/j.polymertesting...
,79[79] DADEJ, K., BIENIAŚ, J., “On fatigue stress-cycle curves of carbon, glass and hybrid carbon/glass-reinforced fibre metal laminates”, International Journal of Fatigue, v. 140, pp. 14, Nov. 2020. doi: http://dx.doi.org/10.1016/j.ijfatigue.2020.105843.
https://doi.org/10.1016/j.ijfatigue.2020...
,80[80] DADEJ, K., SUROWSKA, B., BIENIAŚ, J., “Isostrain elastoplastic model for prediction of static strength and fatigue life of fiber metal laminates”, International Journal of Fatigue, v. 110, pp. 31–41, May 2018. doi: http://dx.doi.org/10.1016/j.ijfatigue.2018.01.009.
https://doi.org/10.1016/j.ijfatigue.2018...
].

At present, there is no relevant standard for the fatigue crack extension test of FMLs at home and abroad. The scholars generally adopt the fatigue test standard ASTM E647 of metal materials, the central crack (MT) test, and the fatigue crack extension test through MTS fatigue test machine and related environmental test box. They use the sine wave cycle loading with stress ratio R = 0.1, frequency f = 10Hz, and observe the fatigue crack expansion through digital microscope. After the experiment, the damage of the lamina can be detected by ultrasonic C scan [81[81] SANTOS, M., SANTOS, J., REIS, P., et al., “Ultrasonic C-scan techniques for the evaluation of impact damage in CFRP”, Materials Testing, v. 63, n. 2, pp. 131–137, Feb. 2021. http://dx.doi.org/10.1515/mt-2020-0020.
https://doi.org/10.1515/mt-2020-0020...
,82[82] HAUFFE, A., HÄHNEL, F., WOLF, K., “Comparison of algorithms to quantify the damaged area in CFRP ultrasonic scans”, Composite Structures, v. 235, pp. 1–11, Mar. 2020. doi: http://dx.doi.org/10.1016/j.compstruct.2019.111791.
https://doi.org/10.1016/j.compstruct.201...
,83[83] VANDENDRIESSCHE, J., ORTA, A.H., VERBOVEN, E., et al., “Probabilistic ultrasound C-scan imaging of barely visible impact damage in CFRP laminates”, Composite Structures, v. 284, pp. 1–13, Mar. 2022. doi: http://dx.doi.org/10.1016/j.compstruct.2022.115209.
https://doi.org/10.1016/j.compstruct.202...
].

3.4. Nondestructive testing technology and index evaluation

Although FMLs has been widely used in engineering companies, but in its production process, due to the process of instability, pores, layer, inclusion, damage, in the use process of defects, also can produce knife marks, scratch, corrosion pit, layered and layered offline damage [84[84] PERVEZ, M.R., AHAMED, M.H., AHMED, M.A., et al., “Autonomous grinding algorithms with future prospect towards SMART manufacturing: a comparative survey”, Journal of Manufacturing Systems, v. 62, pp. 164–185, Jan. 2022. doi: http://dx.doi.org/10.1016/j.jmsy.2021.11.009.
https://doi.org/10.1016/j.jmsy.2021.11.0...
,85[85] KELKEL, B., POPOW, V., GURKA, M., “Inline quantification and localization of transverse matrix cracking in cross-ply CFRP during quasi-static tensile testing by a joint event-based evaluation of acoustic emission and passive IR thermography”, Composites Science and Technology, v. 190, pp. 1–11, Apr. 2020. doi: http://dx.doi.org/10.1016/j.compscitech.2020.108013.
https://doi.org/10.1016/j.compscitech.20...
,86[86] POPOW, V., VOGTMANN, J., GURKA, M., “In-situ characterization of impact damage in carbon fibre reinforced polymers using infrared thermography”, Infrared Physics & Technology, v. 122, pp. 1–13, May 2022. doi: http://dx.doi.org/10.1016/j.infrared.2022.104074.
https://doi.org/10.1016/j.infrared.2022....
,87[87] SONG, H., WANG, Z., ZENG, Y., et al., “Efficient near-field radiofrequency imaging of impact damage on CFRP materials with learning-based compressed sensing”, Materials (Basel), v. 15, n. 17, pp. 1–14, Aug. 2022. doi: http://dx.doi.org/10.3390/ma15175874. PubMed PMID: 36079259.
https://doi.org/10.3390/ma15175874...
], so the FMLs damage detection and testing is particularly important, also gradually caused the researchers and application of extensive attention. For the nondestructive testing methods of FMLs, they mainly include infrared thermal wave detection, ultrasonic detection, acoustic emission detection and microwave nondestructive testing. Various methods have their own characteristics and defects, and they play their own advantages in their respective suitable fields.

3.4.1. Infrared thermal wave detection method

Infrared hot wave nondestructive testing process, need to the detection material heating, detection material internal thermal properties differences and heat conduction discontinuity of the physical surface area form temperature gradient, infrared radiation capacity changes with different temperature, with the aid of infrared thermal imager is measured practice detection and according to the radiation distribution of detection to infer the test of the internal defects [88[88] HEDAYATRASA, S., POELMAN, G., SEGERS, J., et al., “On the application of an optimized Frequency-Phase Modulated waveform for enhanced infrared thermal wave radar imaging of composites”, Optics and Lasers in Engineering, v. 138, pp. 1–12, Mar. 2021. doi: http://dx.doi.org/10.1016/j.optlaseng.2020.106411.
https://doi.org/10.1016/j.optlaseng.2020...
].

Infrared hot wave test technology can conduct nondestructive testing of internal defects such as cracks and stratification of FMLs, but the detection process requires heating and heat transfer to form a temperature gradient, and then produce radiation [89[89] DUA, G., MULAVEESALA, R., KHER, V., et al. “Gaussian windowed frequency modulated thermal wave imaging for non-destructive testing and evaluation of carbon fibre reinforced polymers”, Infrared Physics & Technology, v. 98, pp. 125–131, May 2019. doi: http://dx.doi.org/10.1016/j.infrared.2019.03.007.
https://doi.org/10.1016/j.infrared.2019....
, 90[90] MULAVEESALA, R., ARORA, V., DUA, G., “Pulse compression favorable thermal wave imaging techniques for non-destructive testing and evaluation of materials”, IEEE Sensors Journal, v. 21, n. 12, pp. 12789–12797, Oct. 2020.]. Therefore, it needs a certain time in the detection process, and rapid scanning and detection cannot be carried out.

3.4.2. Ultrasound detection method

Ultrasound detection is one of the most commonly used nondestructive testing methods in the industry. When the ultrasonic wave enters the object, if the defect is encountered, a part of the sound waves will reflect, the receiver analyzes the reflected wave, and can accurately measure its internal defects, and can show the position and size of the internal defects.

However, ultrasonic detection is a kind of contact detection, which requires to add the coupling agent at the probe to reduce the attenuation of the signal when the ultrasonic signal enters the detection material, which will cause pollution to the surface of the test parts, and the rapid scanning detection cannot be carried out, especially for large parts [91[91] ZHANG, X., WU, X., HE, Y., et al., “CFRP barely visible impact damage inspection based on an ultrasound wave distortion indicator”, Composites. Part B, Engineering, v. 168, pp. 152–158, Jul. 2019. doi: yhttp://dx.doi.org/10.1016/j.compositesb.2018.12.092.
https://doi.org/10.1016/j.compositesb.20...
, 92[92] HE, Y., CHEN, S., ZHOU, D., et al., “Shared excitation based nonlinear ultrasound and vibrothermography testing for CFRP barely visible impact damage inspection”, IEEE Transactions on Industrial Informatics, v. 14, n. 12, pp. 5575–5584, Dec. 2018. doi: http://dx.doi.org/10.1109/TII.2018.2820816.
https://doi.org/10.1109/TII.2018.2820816...
].

3.4.3. Acoustic emission detection method

The AE detection method is a detection method to assess the material performance and structural integrity by receiving and analyzing the AE signals of a material. The essence of AE is the stress wave phenomenon caused by the rapid release of strain caused by crack expansion, plastic deformation or phase change in the material.

The acoustic emission detection technology can effectively detect the internal defects and damage types of the composite material, but the position and direction of the defects do not affect the detection effect of the acoustic emission, that is, the acoustic emission detection technology cannot detect the position of the defect and the size of the defect [93[93] ŠOFER, M., CIENCIALA, J., FUSEK, M., et al., “Damage analysis of composite CFRP tubes using acoustic emission monitoring and pattern recognition approach”, Materials (Basel), v. 14, n. 4, pp. 510–518, Oct. 2021. doi: http://dx.doi.org/10.3390/ma14040786. PubMed PMID: 33562336.
https://doi.org/10.3390/ma14040786...
, 94[94] XU, J., WANG, W., HAN, Q., et al., “Damage pattern recognition and damage evolution analysis of unidirectional CFRP tendons under tensile loading using acoustic emission technology”, Composite Structures, v. 238, pp. 1–10, Apr. 2020. doi: http://dx.doi.org/10.1016/j.compstruct.2020.111948.
https://doi.org/10.1016/j.compstruct.202...
].

3.4.4. Microwave nondestructive testing method

Microwave without detection is a new non-contact, the pollution of rapid detection and monitoring technology, through the microwave reflection, scattering, diffraction, transmission, Doppler effect and other physical characteristics and the dielectric constant and loss of detected material to change the electromagnetic characteristics to measure the change of microwave basic parameters, the performance of the material, the defect of the power detection.

According to the different principles of microwave detection, microwave detection can be divided into microwave penetration method, microwave scattering method, microwave reflection method, etc. Li, and other scholars elaborated on the principles, advantages and defects of various methods in [95[95] SHRIFAN, N.H.M.M., AKBAR, M.F., ISA, N.A.M., “Prospect of using artificial intelligence for microwave nondestructive testing technique: a review”, IEEE Access: Practical Innovations, Open Solutions, v. 7, pp. 110628–110650, Aug. 2019. doi: http://dx.doi.org/10.1109/ACCESS.2019.2934143.
https://doi.org/10.1109/ACCESS.2019.2934...
,96[96] SIANG, T.W., FIRDAUS AKBAR, M., NIHAD JAWAD, G., et al., “A past, present, and prospective review on microwave nondestructive evaluation of composite coatings”, Coatings, v. 11, n. 8, pp. 1–25, July 2021. doi: http://dx.doi.org/10.3390/coatings11080913.
https://doi.org/10.3390/coatings11080913...
,97[97] LI, D., ZHOU, J., OU, J., “Damage, nondestructive evaluation and rehabilitation of FRP composite-RC structure: a review”, Construction & Building Materials, v. 271, pp. 1–27, Feb. 2021. doi: http://dx.doi.org/10.1016/j.conbuildmat.2020.121551.
https://doi.org/10.1016/j.conbuildmat.20...
,98[98] JAMES, R., FAISAL HAIDER, M., GIURGIUTIU, V., et al., “A simulative and experimental approach toward Eddy current nondestructive evaluation of manufacturing flaws and operational damage in CFRP composites”, Journal of Nondestructive Evaluation, v. 3, n. 1, pp. 1–18, Oct. 2020.].

4. APPLICATION OF NUMERICAL SIMULATION TECHNOLOGY IN PERFORMANCE ANALYSIS AND INDEX EVALUATION

FMLs performance test time is long, the sample index cost is high, in order to reduce the test cost, improve the reliability of the test, the scholars constantly explore through the finite element simulation technology analysis of the mechanical properties of FMLs, and through the stress analysis combined with appropriate strength failure criterion and damage criterion and damage evolution law to judge the material damage process [99[99] TURON, A., CAMANHO, P.P., COSTA, J., et al., “A damage model for the simulation of delamination in advanced composites under variable-mode loading”, Mechanics of Materials, v. 38, n. 11, pp. 1072–1089, Nov. 2006. doi: http://dx.doi.org/10.1016/j.mechmat.2005.10.003.
https://doi.org/10.1016/j.mechmat.2005.1...
, 100[100] LI, X., MA, D., LIU, H., et al., “Assessment of failure criteria and damage evolution methods for composite laminates under low-velocity impact”, Composite Structures, v. 207, pp. 727–739, Jan. 2019. doi: http://dx.doi.org/10.1016/j.compstruct.2018.09.093.
https://doi.org/10.1016/j.compstruct.201...
]. Since the metal layer of FMLs is elastic-plastic, while the fiber layer is considered to be approximately linear elastic, the traditional classical theoretical model of carbon fiber laminates is not suitable for the mechanical property model after the combination of the two, so the research on the failure behavior of FMLs needs to be further improved.

The comprehensive performance of FMLs is not only related to the properties of fibers, matrix and metal, but also closely related to the arrangement of fibers, the interface binding strength of fiber layer/metal layer, shear strength, etc. [101[101] MAMALIS, D., OBANDE, W., KOUTSOS, V., et al., “Novel thermoplastic fibre-metal laminates manufactured by vacuum resin infusion: the effect of surface treatments on interfacial bonding”, Materials & Design, v. 162, pp. 331–344, Dec. 2019. doi: http://dx.doi.org/10.1016/j.matdes.2018.11.048.
https://doi.org/10.1016/j.matdes.2018.11...
,102[102] DROŹDZIEL, M., PODOLAK, P., NARDI, D., et al., “The mechanical effects of kissing bonding defects in hybrid metal-composite laminates”, Composite Structures, v. 269, pp. 1–14, Aug. 2021. doi: http://dx.doi.org/10.1016/j.compstruct.2021.114027.
https://doi.org/10.1016/j.compstruct.202...
,103[103] HUSSAIN, M., IMAD, A., NAWAB, Y., et al., “Effect of matrix and hybrid reinforcement on fibre metal laminates under low-velocity impact loading”, Composite Structures, v. 288, pp. 1–14, May 2022. doi: http://dx.doi.org/10.1016/j.compstruct.2022.115371.
https://doi.org/10.1016/j.compstruct.202...
,104[104] STRAZNICKY, P.V., LALIBERTÉ, J.F., POON, C., et al., “Applications of fiber-metal laminates”, Polymer Composites, v. 21, n. 4, pp. 558–567, Apr. 2000. doi: http://dx.doi.org/10.1002/pc.10211.
https://doi.org/10.1002/pc.10211...
]. The related test methods are introduced in detail in the mechanical properties test, and this section only introduces the constitutive model and failure criteria.

4.1. Conductive model of metal layer and failure criteria

FMLs, the metal layer mostly using aluminum alloy, titanium alloy ductility good metal, therefore, the metal layer using isotropic elastic-plastic model, applied stress-strain model to show strain reinforcement behavior, using delay damage rule to judge the initial damage [105[105] XU, L., KONG, L., WANG, J., et al., “Stimulation of AMPK prevents degeneration of photoreceptors and the retinal pigment epithelium”, Proceedings of the National Academy of Sciences of the United States of America, v. 115, n. 41, pp. 10475–10480, Feb. 2018. doi: http://dx.doi.org/10.1073/pnas.1802724115. PubMed PMID: 30249643.
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], namely the material in the loading process of plastic deformation, cause internal microporous and micro crack initiation, extension and bureau level, is the material stiffness is reduced, performance degradation. Then, based on the mechanical theory of continuum medium damage, the damage process was analyzed, and the stiffness damage variable changed from 0 to 1, representing the process from initial injury to complete fracture.

4.2. Constitutive model of the fiber layer, and the failure criterion

The commonly used failure models of carbon fiber composites are Tsai-Hill strength criteria, Tsai-Wu failure criteria, Hashin model, Linde model, etc. The Tsai-Hill strength criterion takes the longitudinal strength, transverse strength and shear strength as the failure criteria, and no composite materials with different tensile properties are considered [107[107] RIKARDS, R., BLEDZKI, A.K., EGLAJS, V., et al., “Elaboration of optimal design models for composite materials from data of experiments”, Mechanics of Composite Materials, v. 28, n. 4, pp. 295–304, Aug. 1993. doi: http://dx.doi.org/10.1007/BF00616154.
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]. LINDE et al. [110[110] LINDE, P., DE, B.H., “Modelling of inter-rivet buckling of hybrid composites”, Composite Structures, v. 7, n.2, pp. 221–228, May. 2006. Dio: https://doi.org/10.1016/j.compstruct.2005.11.062.
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] modified the Hashin model for the fiber layer.

4.2.1. Tsai-Wu destruction criteria

The Tsai-Wu damage criterion is the most comprehensive description of composite material destruction in the existing criteria [111[111] ARRUDA, M.R.T., FERNANDES, L.A., CASTRO, L., et al., “Tsai-Wu based orthotropic damage model”, Composites Part C: Open Access, v. 4, pp. 1–14, Mar. 2021.]. Other damage criteria and models can be obtained by simplifying the Tsai-Wu under specific loading and stress conditions [112[112] CHEN, X., SUN, X., CHEN, P., et al., “Rationalized improvement of Tsai-Wu failure criterion considering different failure modes of composite materials”, Composite Structures, v. 256, pp. 1–11, Jan. 2021. doi: http://dx.doi.org/10.1016/j.compstruct.2020.113120.
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].

The Tsai-Wu criterion reduces the disruption to a higher-order tensor polynomial, expressed as

(1)Fiσi+Fjσj+Fkσk+Fijσiσj+Fjiσjσi+Fiiσi2+Fijkσiσjσk+=1(i,j,k=1,2,6)

Where, σi, σj, σk is the stress vector and Fi, Fij, Fijk is the strength tensor coefficient of material characterization.

The more items that are included in the polynomial of the Tsai-Wu destruction criterion, the higher the computational accuracy, but the greater the cost of determining the tensor coefficient. Therefore, in the finite element analysis using the Tsai-Wu intensity criterion, it is easier to achieve damage analysis by using the degradation criteria of CHANG et al., DUTTON et al., and SHOKRIEH et al. [116[116] CHANG, F.K., LESSARD L.B., “Damage Tolerance of Laminated Composites Containing an Open Hole and Subjected to Compressive Loadings: Part I—Analysis”, Journal of Composite Materials, v. 25, n. 1, pp. 2–43, Jul. 2016. doi: https://doi.org/10.1177/002199839102500.
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,119[119] SHOKRIEH, M.M., LESSARD, L.B., “Progressive fatigue damage modeling of composite materials, Part I: Modeling”, Journal of composite materials, v. 34, n. 13, pp. 1056–1080, Jul. 2016. dio: https://doi.org/10.1177/002199830003401301.
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].

4.2.2. Hashin model

Hashin The model specifies the destruction criteria of fiber composites under planar stress. The model considers that the composite material is orthogonal anisotropic material. The injury initiation is based on four main failure modes, namely, fiber tensile fracture, fiber compression buckling, matrix tensile fracture and shear failure of matrix fiber, which are specifically expressed as follows:

Fiber tensile fracture (ɛ11 ≤ 0)

(2)F12=(ε11ε11f,t)2+(ε12ε12f)2+(ε13ε13f)2

Fiber compression in flexion (ɛ11 ≤ 0)

(3)F12=(ε11ε11f,c)21

Basrix tensile fracture (ɛ22 + ɛ33 ≥ 0)

(4)F22=(ε22+ε33ε22f,tε33f,t)2ε22ε33(ε23f)2+(ε12ε12f)2+(ε13ε13f)2+(ε23ε23f)21

Basal fiber shear failure (ɛ22 + ɛ33 < 0)

(5)F22=(ε22+ε33ε22f,cε33f,c)2+ε22+ε33ε22f,c(ε22f,c(2ε12f,c)21)ε22ε33(ε13f)2+(ε12ε12f)2+(ε13ε13f)2+(ε23ε23f)21

4.2.3. Linde model

Linde The model takes the ultimate strain as the criterion for damage, and believes that both the tensile and compression properties of the material are broken. The model assumes that the material has continuous damage, mainly considers the damage of the fiber and the matrix, so that the destruction process of the fiber and the matrix is described by two injuries [121[121] HU, C., SANG, L., JIANG, K., et al., “Experimental and numerical characterization of flexural properties and failure behavior of CFRP/Al laminates”, Composite Structures, v. 281, pp. 1–11, Feb. 2022. doi: http://dx.doi.org/10.1016/j.compstruct.2021.115036.
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], the matrix is expressed as:

Damage and failure of the fibers

(6)εf=ε11f,tε11f,c(ε11)2+[ε11f,t(ε11f,t)2ε11f,c]ε11>ε11f,t

Damage failure of the matrix

(7)εm=ε22f,tε22f,c(ε22)2+[ε22f,t(ε22f,t)2ε22f,c]ε22+(ε22f,t)2ε12f,c(ε12)2>ε22f,t

4.3. Establishment of the interface model and the damage criterion

FMLs are laminated structure, and stratification is one of the main forms of failure. The weak binding force at the interface between metal layer and fiber layer is the key factor controlling the failure of lamina, which is closely related to the macroscopic mechanical properties and interfacial properties of FMLs [123[123] LI, B., MA, X., ZHANG, G., et al., “Enhancement of gas production from natural gas hydrate reservoir by reservoir stimulation with the stratification split grouting foam mortar method”, Journal of Natural Gas Science and Engineering, v. 81, pp. 1–17, Sept. 2020. doi: http://dx.doi.org/10.1016/j.jngse.2020.103473.
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].

The interfacial layer of FMLs is relatively thin, the nature of the thickness direction cannot be ignored, and the stress and strain analysis is relatively difficult. In addition, the continuity assumption is no longer applicable to the stratification and expansion of inter-layer destruction. Scholars initially tried to use zero thickness unit to solve the problem of unit division in the thickness direction [126[126] DAY, R.A., POTTS, D.M., “Zero thickness interface elements—numerical stability and application”, International Journal for Numerical and Analytical Methods in Geomechanics, v. 18, n., 10, pp. 689–708, Oct. 1994. doi: http://dx.doi.org/10.1002/nag.1610181003.
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], and then tried to equivalent the interface layer to normal and tangential orthogonal springs to simulate the debonding problem of composite materials [128[128] DAŞDEMIR, A., “A spring-layer model for a bi-layered plate-strip with initial stress through imperfect contact interface”, Sound and Vibration, v. 53, n. 3, pp. 65–74, June 2019. doi: http://dx.doi.org/10.32604/sv.2019.04087.
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], and achieved certain results, but did not reflect the interaction between normal and tangential when the interface damage.

Cohesin model is widely used as a composite damage model by researchers to simulate the multilayer interface. It is on the basis of elastic, interface element model developed a thickness of interface unit, the interface unit by defining the appropriate interface stiffness, failure strength and fracture toughness between the material mechanical properties parameters, and describe the metal layer and fiber layer on the surface of the cohesion and separation of the relative only relationship, and study the interface damage evolution law and the influence on the overall performance of composite materials [130[130] MARKO, J.F., DE LOS RIOS, P., BARDUCCI, A., et al., “DNA-segment-capture model for loop extrusion by structural maintenance of chromosome (SMC) protein complexes”, Nucleic Acids Research, v. 47, n. 13, pp. 6956–6972, June 2019. doi: http://dx.doi.org/10.1093/nar/gkz497. PubMed PMID: 31175837.
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]. In the cohesive model, the stress-strain behavior is the traction-separation mode, and the area surrounded by the traction-separation curve and the displacement coordinate is the interlayer fracture toughness, as shown in Figure 1.

Figure 1.
The constitutive model of cohesive force element.

In the cohesion model, the secondary nominal strain criterion (quade damage) was used to determine the onset of injury. The energy-based Benzeggagh-Kenane fracture criterion (B-K law) is more accurate in predicting the evolution of hierarchical damage in the interface.

In the modeling process of FMLs, it is generally used to establish a thin layer of finite thickness between the metal layer and the fiber layer, assign the cohesive material properties, and realize the unit common nodes and transfer loads. This method can better simulate the layered damage failure than establishing the surface-surface cohesive contact [133[133] LIU, Z., “Deep material network with cohesive layers: Multi-stage training and interfacial failure analysis”, Computer Methods in Applied Mechanics and Engineering, v. 363, pp. 1–15, May 2020.].

4.4. Macroscopic and detailed view simulation

The damage evolution process of the composite material is multi-scale and cross-level, and its structural properties and damage failure mechanism not only depend on the material performance of each component of the composite material, but also depend on its fine structural characteristics [134[134] JOUSSET, P., REINSCH, T., RYBERG, T., et al., “Dynamic strain determination using fibre-optic cables allows imaging of seismological and structural features”, Nature Communications, v. 9, n. 1, pp. 2509, Jul. 2018. doi: http://dx.doi.org/10.1038/s41467-018-04860-y. PubMed PMID: 29970883.
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]. A single macroscopic or fine-scale simulation method is difficult to accurately reflect the damage and failure characteristics of composite composites.

The macroscopic simulation does not discuss the difference between fiber and matrix, but mainly discusses the mechanical problems of stretching, bending, flexion and fatigue under the influence of FMLs structure. According to the main problems of the macroscopic simulation study, a variety of strength failure theories are also put forward. However, the macroscopic simulation does not involve the micro mechanism of material failure, but predicts the failure behavior of the composite material structure through the material failure criteria [137[137] SUN, L., TIE, Y., HOU, Y., et al., “Prediction of failure behavior of adhesively bonded CFRP scarf joints using a cohesive zone model”, Engineering Fracture Mechanics, v. 228, pp. 1–16, Apr. 2020. doi: http://dx.doi.org/10.1016/j.engfracmech.2020.106897.
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]. Therefore, the macroscopic simulation is widely used in engineering practice and plays an important role.

However, the mechanical properties of FMLs are their unique anisotropy, and there is a strong correlation between their failure form and its anisotropy, especially the carbon fiber reinforced composite material, which is composed of fiber and matrix, and the accumulation of microscopic defects and cracks determines the characteristics of macroscopic failure [140[140] YANG, J., MU, Z., YANG, S.Q., et al., “Experimental investigation of microscopic crack development and damage characteristics of sandstone based on acoustic emission characteristic parameters”, Geomechanics and Geophysics for Geo-Energy and Geo-Resources, v. 8, n. 2, pp. 1–16, Aug. 2022. doi: http://dx.doi.org/10.1007/s40948-022-00361-x.
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,142[142] MENG, J., WANG, Y., YANG, H., et al. “Mechanical properties and internal microdefects evolution of carbon fiber reinforced polymer composites: cryogenic temperature and thermocycling effects”, Composites Science and Technology, v. 191, pp. 1–14, May 2020.]. In the process of finite element simulation, the researchers use the single cell model under the fine scale, and build the internal fiber bundle of the material and woven or woven geometry parameters, pretreatment through CAD modeling and the finite element meshing software, and adopt appropriate failure criteria based on different failure modes to calculate the stress and strain distribution after damage on the mesoscale [143[143] UMAR, M., QAYYUM, F., FAROOQ, M.U., et al., “Qualitative investigation of damage initiation at meso-scale in Spheroidized C45EC steels by using crystal plasticity-based numerical simulations”, Journal of Composites Science, v. 5, n. 8, pp. 1–18, Jan. 2021. doi: http://dx.doi.org/10.3390/jcs5080222.
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].

5. FORECASTING AND OUTLOOK

With the increasing consumption of FMLs in aerospace, rail transit and ships and the continuous improvement of application requirements, the requirements for FLs test methods and index evaluation have also brought challenges, and the requirements for high efficiency and reliability of performance testing are getting higher and higher. The future work can be carried out in the following aspects.
  1. Carry out the performance test and study of FMLs of large size, large thickness, large curvature and complex structures. In the fields of aerospace, rail transit, shipping and other, the demand for large size, large thickness and complex structure FMLs is increasing, and the requirements for their reliability are also getting higher and higher. The relevant FLs, performance testing, related mechanism research and engineering application research will become the focus of research and application in recent years.

  2. Conduct performance tests under extreme conditions. FMLs has more extensive requirements in high temperature, high pressure, high speed, high frequency, low temperature, extreme humidity and other fields. Common performance testing equipment, systems, schemes, and standards cannot meet the requirements of performance testing under the above extreme conditions, so it is necessary to accelerate the research and standard formulation of FMLs testing equipment under extreme conditions.

  3. Carry out rapid ND destructive research with high sensitivity. The commonly used nondestructive testing technology such as infrared, ultrasonic, penetration, acoustic emission, microwave can meet the requirements of internal defects detection, but with the application of FMLs is more and more widely, high value-added products of detection content, detection accuracy, detection cycle requirement is more and more high, need to carry out high sensitivity of rapid nondestructive testing technology research.

  4. Carry out numerical simulation research on molecular scale. At present, the macro and micro scale resin simulation of the mechanical properties and damage of FMLs has certain limitations. With the increasing demands of the industry on the comprehensive properties of FMLs, it is imperative to develop a more complete constitutive model of FMLs and analyze the mechanical properties and damage mechanism of FMLs at the molecular scale.

6. ACKNOWLEDGMENTS

The research of this paper is made possible by the generous support from Tianjin Sino-German University of Applied Sciences.

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Publication Dates

  • Publication in this collection
    03 Mar 2023
  • Date of issue
    2023

History

  • Received
    11 Jan 2023
  • Accepted
    16 Jan 2023
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